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Polymer Science Series B

, Volume 53, Issue 3–4, pp 125–131 | Cite as

Copolymerization of N-vinylpyrrole-2-carbaldehydes with styrene, N-vinylpyrrolidone, and ethylene glycol vinyl glycidyl ether

  • I. V. Tatarinova
  • L. V. Morozova
  • M. V. Markova
  • A. M. Vasil’tsov
  • A. V. Ivanov
  • G. F. Myachina
  • S. S. Khutsishvili
  • A. I. Mikhaleva
  • B. A. Trofimov
Polymerization

Abstract

Polyfunctional reactive copolymers of N-vinylpyrrole-2-carbaldehydes with styrene, N-vinylpyrrolidone, and ethylene glycol vinyl glycidyl ether are synthesized in the presence of AIBN (2 wt %, 80°C, 50 h) with a yield of up to 98% and a molecular mass of up to 4800. The copolymers show paramagnetic behavior (N = 2.0 × 1015−2.0 × 1017 g−1) and possess the properties of organic semiconductors (σ = 0.9 × 10−11–2.8 × 10−7 S/cm after doping with I2).

Keywords

Copolymerization Polymer Science Series AIBN Paramagnetic Center Turbidimetric Titration 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Pleiades Publishing, Ltd. 2011

Authors and Affiliations

  • I. V. Tatarinova
    • 1
  • L. V. Morozova
    • 1
  • M. V. Markova
    • 1
  • A. M. Vasil’tsov
    • 1
  • A. V. Ivanov
    • 1
  • G. F. Myachina
    • 1
  • S. S. Khutsishvili
    • 1
  • A. I. Mikhaleva
    • 1
  • B. A. Trofimov
    • 1
  1. 1.Favorsky Institute of Chemistry, Siberian BranchRussian Academy of SciencesIrkutskRussia

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