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Branched polyphenylquinoxalines containing naphthoxazine-5,8-disulfonic acid groups

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Abstract

Branched carboxylated polyphenylquinoxalines are prepared via the interaction of tris(α-diketone), 4,4′-bis(phenylglyoxalyl)benzyl, with an equimolar amount of 3,4-diaminobenzoic acid and subsequent interaction of the reaction product with an equimolar amount of bis(o-phenylenediamines). Polymeranalogous transformations of these polymers with 1-amino-8-naphthol-3,6-disulfonic acid sodium salt monohydrate in Eaton’s reagent yield earlier undescribed branched polyphenylquinoxalines containing side naphthoxazine-5,8-disulfonic acid groups.

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Authors and Affiliations

  1. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, 119991, Russia

    A. L. Rusanov, E. A. Solodova, E. G. Bulycheva & N. M. Belomoina

Authors
  1. A. L. Rusanov
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  2. E. A. Solodova
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  3. E. G. Bulycheva
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  4. N. M. Belomoina
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Corresponding author

Correspondence to E. G. Bulycheva.

Additional information

Original Russian Text © A.L. Rusanov, E.A. Solodova, E.G. Bulycheva, N.M. Belomoina, 2010, published in Russian in Vysokomolekulyarnye Soedineniya, Ser. B, 2010, Vol. 52, No. 7, pp. 1190–1195.

This work was supported by the Russian Foundation for Basic Research, project no. 08-03-00323.

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Rusanov, A.L., Solodova, E.A., Bulycheva, E.G. et al. Branched polyphenylquinoxalines containing naphthoxazine-5,8-disulfonic acid groups. Polym. Sci. Ser. B 52, 391–396 (2010). https://doi.org/10.1134/S1560090410070031

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  • DOI: https://doi.org/10.1134/S1560090410070031

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