Polymer Science Series B

, Volume 52, Issue 3–4, pp 193–197 | Cite as

Polymerization of 1,4-bis[2-(N-vinyl)pyrrolyl]benzene

  • B. A. Trofimov
  • M. V. Markova
  • L. V. Morozova
  • A. I. Mikhaleva
  • E. Yu. Shmidt
  • N. V. Zorina
  • Sang Heon Hyun
Polymerization

Abstract

Polymers of 1,4-bis[2-(N-vinyl)pyrrolyl]benzene with free N-vinyl groups in side chains are synthesized in the presence of AIBN (2–5 wt %, 70°C) with a yield of up to 34% and a molecular mass of up to 11.5 × 103. In the presence of cationic catalysts (Me3SiCl, the LiBF4-dimethoxyethane system, and BF3 · OEt2), 1,4-bis[2-(N-vinyl)pyrrolyl]benzene gives macromolecules with alternating 1,2-pyrrolene and ethylidene units in the backbone with yields of 80, 44, and 33%, respectively. The polymers demonstrate paramagnetic and luminescent properties.

Keywords

Pyrrole Polymer Science Series AIBN Pyrrole Ring Role Ring 

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Copyright information

© Pleiades Publishing, Ltd. 2010

Authors and Affiliations

  • B. A. Trofimov
    • 1
  • M. V. Markova
    • 1
  • L. V. Morozova
    • 1
  • A. I. Mikhaleva
    • 1
  • E. Yu. Shmidt
    • 1
  • N. V. Zorina
    • 1
  • Sang Heon Hyun
    • 2
  1. 1.Favorsky Institute of Chemistry, Siberian BranchRussian Academy of SciencesIrkutskRussia
  2. 2.Display Device & Material LaboratorySamsung Advanced Institute of TechnologyNongseo-Dong, Giheung-Gu, Yongin, Gyeonggi-DoSouth Korea

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