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Structured polyphenylenes as carriers of palladium nanoparticles used as selective hydrogenation catalysts

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Abstract

Structured polyphenylenes that are used as matrices for immobilization of palladium nanoparticles are synthesized through the cyclocondensation of acetylaromatic compounds followed by structuring at different temperatures and, as a result, different crosslink densities. The relationship between the structure and structuring temperature of the polymers is investigated. It is shown that the sizes of palladium nanoparticles immobilized in polyphenylene matrices depend on the conditions of polymer structuring. The resulting catalytic systems are examined for the selective hydrogenation of triple bonds in acetylene alcohols.

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Reference

  1. J. H. Fendler, Nanoparticles and Nanostructured Films: Preparation, Characterization and Applications (Wiley-VCH, New York, 1998).

    Book  Google Scholar 

  2. I. Tsvetkova, E. Sulman, V. Matveeva, et al., Top. Catal. 39, 187 (2006).

    Article  Google Scholar 

  3. C. Mueller, M. Nijkamp, and D. Vogt, Eur. J. Inorg. Chem. 20, 4011(2005).

    Google Scholar 

  4. L. M. Bronstein, in Encyclopedia of Nanoscience and Nanotechnology, Ed. by H. S. Nalwa (Stevenson Ranch, 2004), Vol. 7, p. 193.

    CAS  Google Scholar 

  5. C. Chen, T. Serizawa, and M. Akashi, Chem. Mater. 14, 2232 (2002).

    Article  CAS  Google Scholar 

  6. Y. Nakao and K. Kaeriyama, J. Colloid Interface Sci. 110, 82(1986).

    Article  Google Scholar 

  7. L. Liz-Marzan and I. Lado-Tourino, Langmuir 12, 3585 (1996).

    Article  CAS  Google Scholar 

  8. L. Yeung and R. Crooks, Nano Lett. 1, 14 (2001).

    Article  CAS  Google Scholar 

  9. A. Fahmi, A. D’Aléo, R. Williams, et al., Langmuir 23, 7831 (2007).

    Article  CAS  Google Scholar 

  10. J. Worden, Q. Dai, and Q. Huo, Chem. Commun., 1536 (2006).

  11. N. Toshima, M. Harada, T. Yonezawa, et al., J. Phys. Chem. 95, 7448 (1991).

    Article  CAS  Google Scholar 

  12. J. Bradley, E. Hill, S. Behal, and C. Klein, Chem. Mater. 4, 1234(1992).

    Article  Google Scholar 

  13. S. Pathak, M. Greci, R. Kwong, et al., Chem. Mater. 12, 1985 (2000).

    Article  CAS  Google Scholar 

  14. A. Biffis and L. Minati, J. Catal. 236, 405 (2005).

    Article  CAS  Google Scholar 

  15. D. Svergun, E. Shtykova, A. Dembo, et al., J. Chem. Phys. 109, 1109(1998).

    Article  Google Scholar 

  16. X. Jiang, D. Xiong, Y. An, et al., J. Polym. Sci., Part A: Polym. Chem. 45, 2812 (2007).

    Article  CAS  Google Scholar 

  17. V. Pol, H. Grisaru, and A. Gedanken, Langmuir 21, 3635 (2005).

    Article  CAS  Google Scholar 

  18. L. Cen, K. Neoh, and E.-T. Kang, Adv. Mater. (Wein-heim, Fed. Repub. Ger.) 17, 1656 (2005).

    Article  CAS  Google Scholar 

  19. J. Ou, C. Chang, Y. Sung, et al., Colloids Surf., A 305, 36 (2007).

    Article  CAS  Google Scholar 

  20. L.-S. Zhong, J.-S. Hu, Z.-M. Cui, et al., Chem. Mater. 19, 4557 (2007).

    Article  CAS  Google Scholar 

  21. H. Mohammed and D. Shipp, Macromol. Rapid Commun. 27, 1774(2006).

    Article  Google Scholar 

  22. N. Semagina, A. Bykov, E. Sulman, et al., J. Mol. Catal., A 208, 273(2004).

    Google Scholar 

  23. I. Beletskaya, A. Kashin, I. Khotina, and A. Khokhlov, Synlett. 10, 1548 (2008).

    Google Scholar 

  24. A. Dokoutchaev, J. James, S. Koene, et al., Chem. Mater. 11, 2389(1999).

    Article  Google Scholar 

  25. C.-W. Chen, T. Serizawa, and M. Akashi, Chem. Mater. 11, 1381 (1999).

    Article  CAS  Google Scholar 

  26. J. Zhang, S. Xu, and E. Kumacheva, J. Am. Chem. Soc. 126, 7908 (2004).

    Article  CAS  Google Scholar 

  27. M. Besson and P. Gallezot, Catal. Today 81, 547 (2003).

    Article  CAS  Google Scholar 

  28. A. Papp, K. Miklós, P. Forgo, and A. Molnár, J. Mol. Catal., A 229, 107(2005).

    Google Scholar 

  29. L. Groeschel, Ind. Eng. Chem. Res. 44, 9064 (2005).

    Article  CAS  Google Scholar 

  30. L. Pachon and G. Rothenberg, Appl. Organomet. Chem. 22, 288 (2008).

    Article  Google Scholar 

  31. L. Nikoshvili, E. Sulman, G. Demidenko, et al., in Catalytic Organic Reactions, Ed. by S. R. Schmidt (CRC, 2007), p. 177.

  32. L. Bronstein, V. Matveeva, M. Sulman, et al., Nanocatalysis, 51 (2006).

  33. L. Bronstein, S. Sidorov, and P. Valetsky, Russ. Chem. Rev. 73, 501 (2004).

    Article  CAS  Google Scholar 

  34. L. Bronstein, G. Goerigk, M. Kostylev, et al., J. Phys. Chem., B 108, 18234 (2004).

    Article  CAS  Google Scholar 

  35. L. Bronstein, V. Matveeva, and E. Sulman, Nanoparticulate Catalysts Based on Nanostructured Polymers. Nanoparticles and Catalysis, Ed. by D. Astruc (Wiley-VCH, Weinheim, 2008), p. 93.

    Google Scholar 

  36. M. Teplyakov, Usp. Khim. 2, 344 (1979).

    Google Scholar 

  37. C. Wagner, A. Naumkin, and A. Kraut-Vass, NIST X-Ray Photoelectron Spectroscopy Database. NIST Standard Reference Database 20. Version 3.4 (Web Version) (2004).

  38. L. Ruzicka, Helv. Chim. Acta 21, 364 (1938).

    Article  CAS  Google Scholar 

  39. H. Mayer, Helv. Chim. Acta 46, 963 (1963).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Nesmeyanov Institute of Organoelement Compounds, RAN, ul. Vavilova 28, Moscow, 119991, Russia

    D. A. Rud’, T. P. Loginova, A. V. Naumkin, Yu. L. Slovokhotov, M. G. Sul’man & I. A. Khotina

  2. Tver State Technical University, nab. Afanasiya. Nikitina 22, Tver, 170026, Russia

    L. Zh. Nikoshvili & V. G. Matveeva

Authors
  1. D. A. Rud’
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  2. L. Zh. Nikoshvili
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  3. T. P. Loginova
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  4. A. V. Naumkin
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  5. Yu. L. Slovokhotov
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  6. V. G. Matveeva
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  7. M. G. Sul’man
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  8. I. A. Khotina
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Correspondence to D. A. Rud’.

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Original Russian Text © D.A. Rud’, L.Zh. Nikoshvili, T.P. Loginova, A.V. Naumkin, Yu.L. Slovokhotov, V.G. Matveeva, M.G. Sul’man, I.A. Khotina, 2010, published in Russian in Vysokomolekulyarnye Soedineniya, Ser. B, 2010, Vol. 52, No. 1, pp. 141–148.

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Rud’, D.A., Nikoshvili, L.Z., Loginova, T.P. et al. Structured polyphenylenes as carriers of palladium nanoparticles used as selective hydrogenation catalysts. Polym. Sci. Ser. B 52, 49–56 (2010). https://doi.org/10.1134/S1560090410010070

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  • DOI: https://doi.org/10.1134/S1560090410010070

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