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Polymer Science Series B

, Volume 51, Issue 11–12, pp 452–456 | Cite as

Copolymerization of vinyl chloride with 1-(vinyloxyalkoxy)propylene oxides-2,3: Solvophobic effects of solvents

  • T. V. Raskulova
  • L. I. Volkova
  • G. F. Myachina
  • A. K. Khaliullin
Polymerization
  • 22 Downloads

Abstract

The influence of solvophobic effects of aprotic solvents on the reactivity of 1-(vinyloxyalkoxy)propylene oxides-2,3 in free-radical copolymerization with vinyl chloride has been studied by dynamic light scattering. It has been shown that the association of copolymer macromolecules in aprotic solvents results in the reduced reactivity of 1-(vinyloxyalcoxy)propylene oxides-2,3. This effect can be explained by a decrease in their local concentration in the vicinity of the reaction center.

Keywords

Polymer Science Series Vinyl Chloride Hydrodynamic Radius Propylene Oxide Reactivity Ratio 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Pleiades Publishing, Ltd. 2009

Authors and Affiliations

  • T. V. Raskulova
    • 1
  • L. I. Volkova
    • 2
  • G. F. Myachina
    • 2
  • A. K. Khaliullin
    • 2
  1. 1.Angarsk State Technical AcademyAngarsk, Irkutsk oblastRussia
  2. 2.Favorsky Institute of Chemistry, Siberian BranchRussian Academy of SciencesIrkutskRussia

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