Polymer Science Series B

, Volume 51, Issue 11–12, pp 452–456 | Cite as

Copolymerization of vinyl chloride with 1-(vinyloxyalkoxy)propylene oxides-2,3: Solvophobic effects of solvents

  • T. V. RaskulovaEmail author
  • L. I. Volkova
  • G. F. Myachina
  • A. K. Khaliullin


The influence of solvophobic effects of aprotic solvents on the reactivity of 1-(vinyloxyalkoxy)propylene oxides-2,3 in free-radical copolymerization with vinyl chloride has been studied by dynamic light scattering. It has been shown that the association of copolymer macromolecules in aprotic solvents results in the reduced reactivity of 1-(vinyloxyalcoxy)propylene oxides-2,3. This effect can be explained by a decrease in their local concentration in the vicinity of the reaction center.


Polymer Science Series Vinyl Chloride Hydrodynamic Radius Propylene Oxide Reactivity Ratio 
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Copyright information

© Pleiades Publishing, Ltd. 2009

Authors and Affiliations

  • T. V. Raskulova
    • 1
    Email author
  • L. I. Volkova
    • 2
  • G. F. Myachina
    • 2
  • A. K. Khaliullin
    • 2
  1. 1.Angarsk State Technical AcademyAngarsk, Irkutsk oblastRussia
  2. 2.Favorsky Institute of Chemistry, Siberian BranchRussian Academy of SciencesIrkutskRussia

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