Advertisement

Polymer Science Series B

, Volume 51, Issue 7–8, pp 283–290 | Cite as

Alternating copolymerization of ethylene with carbon monoxide on a supported palladium catalyst

  • O. M. Chukanova
  • Yu. M. Shul’ga
  • G. P. Belov
Polymerization

Abstract

The kinetics of the alternating copolymerization of ethylene with carbon monoxide has been studied in the presence of a palladium catalyst immolized on a polymer support in various media (methanol, toluene, heptane). In the case of hydrocarbon solvents, the activity of the supported catalyst is commensurable with the activity of a homogeneous system in methanol. The melting temperature of the resulting copolymer and its molecular mass depend on the solvent nature. The IR reflectance spectra of the active palladium complex and the ethylene-carbon monoxide copolymer are measured.

Keywords

Heptane Polymer Science Series Catalytic System Palladium Catalyst Palladium Complex 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    G. P. Belov and E. V. Novikova, Usp. Khim. 73, 292 (2004).Google Scholar
  2. 2.
    C. Bianchini and A. Meli, Coord. Chem. Rev. 225, 35 (2002).CrossRefGoogle Scholar
  3. 3.
    R. A. M. Robertson and D. J. Cole-Hamilton, Coord. Chem. Rev. 225, 67 (2002).CrossRefGoogle Scholar
  4. 4.
    A. Vavasori, L. Toniolo, and G. Cavinato, J. Mol. Catal., A: Chem. 215, 63 (2004).CrossRefGoogle Scholar
  5. 5.
    A. Fabrello, A. Vavasori, F. Acqua, and L. Toniolo, J. Mol. Catal., A: Chem. 276, 211 (2007).CrossRefGoogle Scholar
  6. 6.
    A. Vavasori, G. Cavinato, and L. Toniolo, J. Mol. Catal., A: Chem. 191, 209 (2003).CrossRefGoogle Scholar
  7. 7.
    M. J. Doyle, J. C. Van Ravenswaay-Claasen, G. G. Resenbrand, and R. L. Wife, EU Patent No. 0248483 A2 (1987).Google Scholar
  8. 8.
    P. A. Gautier, R. J. Wijngaarden, and J. J. Keijsper, EU Patent No. 0534570 A1 (1992).Google Scholar
  9. 9.
    J. J. Keijsper, EU Patent No. 0 572087 A1 (1993).Google Scholar
  10. 10.
    A. Sommazzi, G. Luqli, F. Carderazzo, et al., EU Patent No. 0559288 B1 (1993).Google Scholar
  11. 11.
    F. Benetollo, R. Bertani, G. Bombieri, and L. Toniolo, Inorg. Chim. Acta 233, 5 (1995).CrossRefGoogle Scholar
  12. 12.
    G. P. Belov, O. N. Golodkov, and E. V. Novikova, Polymer Science, Ser. A 40, 240 (1998) [Vysokomol. Soedin., Ser. A 40, 419 (1998)].Google Scholar
  13. 13.
    B. J. Lommerts, PhD Thesis (Groningen, 1994).Google Scholar
  14. 14.
    F. Beamish, The Analytical Chemistry of The Noble Metals (Oxford, 1966; Mir, Moscow, 1969), Part 2.Google Scholar
  15. 15.
    G. Cavinato, A. Vavasory, L. Toniolo, and A. Dolmella, Inorg. Chim. Acta 357, 2737 (2004).CrossRefGoogle Scholar
  16. 16.
    C. Bianchini, A. Meli, W. Oberhauser, et al., J. Mol. Catal., A: Chem. 265, 291 (2006).Google Scholar
  17. 17.
    G. A. Holt and J. E. Spruiell, J. Appl. Polym. Sci. 83, 2124 (2002).CrossRefGoogle Scholar
  18. 18.
    E. Drent, J. A. M. Broekhoven, and M. J. Doyle, J. Organomet. Chem. 417, 235 (1991).CrossRefGoogle Scholar
  19. 19.
    S. De Vito, F. Ciardelli, E. Benedetti, and E. Bramanti, Polym. Adv. Technol. 8, 53 (1997).CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2009

Authors and Affiliations

  • O. M. Chukanova
    • 1
  • Yu. M. Shul’ga
    • 1
  • G. P. Belov
    • 1
  1. 1.Institute of Problems of Chemical PhysicsRussian Academy of SciencesChernogolovka, Moscow oblastRussia

Personalised recommendations