Polymer Science Series B

, Volume 49, Issue 9–10, pp 224–228 | Cite as

Polymerization of styrene in the presence of nitroxide radicals of the dihydroimidazole series

  • M. A. Lazarev
  • I. A. Kirilyuk
  • I. A. Grigor’ev
  • D. F. Grishin
Article

Abstract

2,2,5,5-Tetramethyl-4-phenyl-2,5-dihydroimidazole-1-oxyl and 2,2,5,5-tetramethyl-4-phenyl-2,5-dihydroimidazole-3-oxide-1-oxyl have been used as regulators of chain growth in the free-radical polymerization of styrene. It has been shown that the compounds of the dihydroimidazole series function as new living polymerization agents and allow the synthesis of polymers with low polydispersity coefficients and desired molecular masses.

Keywords

Styrene Polymer Science Series AIBN Nitroxide Benzoyl Peroxide 

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References

  1. 1.
    G. V. Korolev and A. P. Marchenko, Usp. Khim. 69, 447 (2000).Google Scholar
  2. 2.
    M. Yu. Zaremskii and V. B. Golubev, Polymer Science, Ser. C 43, 81 (2001) [Vysokomol. Soedin., Ser. C 43, 1689 (2001).Google Scholar
  3. 3.
    D. F. Grishin and L. L. Semenycheva, Usp. Khim. 70, 486 (2001).Google Scholar
  4. 4.
    J. Qiu, B. Charleux, and K. Matyjaszewski, Prog. Polym. Sci. 26, 2083 (2001).CrossRefGoogle Scholar
  5. 5.
    M. Souaille and H. Fisher, Macromolecules 33, 7378 (2000).CrossRefGoogle Scholar
  6. 6.
    A. Studer, K. Harms, Ch. Knoop, et al., Macromolecules 37, 27 (2004).CrossRefGoogle Scholar
  7. 7.
    Y. Miura, N. Nakamura, and I. Taniguchi, Macromolecules 34, 447 (2001).CrossRefGoogle Scholar
  8. 8.
    D. F. Grishin, S. K. Ignatov, A. G. Razuvaev, et al., Polymer Science, Ser. A 43, 989 (2001) [Vysokomol. Soedin., Ser. A 43, 1742 (2001)].Google Scholar
  9. 9.
    D. F. Grishin, L. L. Semenycheva, and E. V. Kolyakina, Dokl. Akad. Nauk 362, 634 (1998)].Google Scholar
  10. 10.
    T. K. Sevast’yanova and L. B. Volodarskii, Izv. Akad. Nauk SSSR, Ser. Khim., No. 10, 2339 (1972).Google Scholar
  11. 11.
    V. A. Reznikov and L. B. Volodarskii, Izv. Ross. Akad. Nauk, Ser. Khim., No. 9, 1654 (1997).Google Scholar
  12. 12.
    A. Weissberger, E. Praskauer, J. Riddik, and E. Toops, Organic Solvents: Physical Properties and Methods of Purification (Wiley, New York, 1986; Inostrannaya Literatura, Moscow, 1958).Google Scholar
  13. 13.
    Encyclopedia of Polymers (Sovetskaya Entsiklopediya, Moscow, 1976), Vol. 1 [in Russian].Google Scholar
  14. 14.
    B. G. Belen’kii and L. Z. Vilenchik, Chromatography of Polymers (Khimiya, Moscow, 1978) [in Russian].Google Scholar
  15. 15.
    V. E. Zubarev, The Method of Spin Traps (Mosk. Gos. Univ., Moscow, 1984) [in Russian].Google Scholar
  16. 16.
    C. E. H. Bawn and S. F. Mellish, Trans. Faraday Soc. 47, 1216 (1951).CrossRefGoogle Scholar
  17. 17.
    J. P. Van Hook and A. V. Tobolsky, J. Am. Chem. Soc. 80, 779 (1958).CrossRefGoogle Scholar
  18. 18.
    A. W. Hui and A. E. Hamielec, J. Apply Polym. Sci 16, 749 (1972).CrossRefGoogle Scholar
  19. 19.
    V. B. Golubev, M. Yu. Zaremskii, A. P. Orlova, and A. V. Olenin, Polymer Science, Ser. A 46, 295 (2004) [Vysokomol. Soedin., Ser. A 46, 491 (2004)].Google Scholar
  20. 20.
    D. F. Grishin, M. A. Lazarev, L. L. Semenycheva, and E. Yu. Nikolaev, Zh. Prikl. Khim. 78, 831 (2005).Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2007

Authors and Affiliations

  • M. A. Lazarev
    • 1
  • I. A. Kirilyuk
    • 2
  • I. A. Grigor’ev
    • 2
  • D. F. Grishin
    • 1
  1. 1.Research Institute of ChemistryNizhni Novgorod State UniversityNizhni NovgorodRussia
  2. 2.Novosibirsk Institute of Organic Chemistry, Siberian DivisionRussian Academy of SciencesNovosibirskRussia

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