Polymerization of methyl methacrylate and vinyl acetate initiated by the manganese carbonyl-1,2-epoxy-4,4,4-trichlorobutane system
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Polymers containing epoxy groups at the ends of macromolecules and in side radicals are prepared through polymerization of methyl methacrylate and vinyl acetate in the presence of the manganese carbonyl-1,2-epoxy-4,4,4-trichlorobutane system. The presence of reinitiation is revealed; it leads to an appreciable increase in the molecular masses of poly(methyl methacrylate) and poly(vinyl acetate) as compared to polymers synthesized in the presence of 2,2′-azo-bis(isobutyronitrile) and 1,2-epoxy-4,4,4-trichlorobutane.
KeywordsPMMA Polymer Science Series Chlorine Atom Methyl Methacrylate AIBN
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