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Preparation of branched cis-1,4-polybutadiene in the presence of a neodymium catalyst

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Abstract

It was shown that branches can be incorporated into linear chains of cis-1,4-polybutadiene produced in the presence of neodymium catalysts. Branched polymers were prepared through the copolymerization of butadiene and a low-molecular-mass polybutadiene macromonomer containing a system of conjugated C=C bonds at chain ends. The incorporation of macromonomer units into the polymer chain was confirmed by the IR spectroscopic analysis of macromonomer-perdeuterobutadiene copolymers.

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Authors and Affiliations

  1. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninskii pr. 29, Moscow, 119991, Russia

    K. L. Makovetskii, V. A. Yakovlev, T. G. Golenko & G. N. Bondarenko

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  1. K. L. Makovetskii
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  2. V. A. Yakovlev
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  3. T. G. Golenko
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  4. G. N. Bondarenko
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Additional information

Original Russian Text © K.L. Makovetskii, V.A. Yakovlev, T.G. Golenko, G.N. Bondarenko, 2006, published in Vysokomolekulyarnye Soedineniya, Ser. B, 2006, Vol. 48, No. 3, pp. 534–539.

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Makovetskii, K.L., Yakovlev, V.A., Golenko, T.G. et al. Preparation of branched cis-1,4-polybutadiene in the presence of a neodymium catalyst. Polym. Sci. Ser. B 48, 61–65 (2006). https://doi.org/10.1134/S1560090406030018

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  • DOI: https://doi.org/10.1134/S1560090406030018

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