Abstract
In 2008, V.Ya. Shevchenko and S.V. Krivovichev built the zeolites series related to paulingite based on the inorganic gene concept and predicted a new zeolite named ISC-1 (Institute of Silicate Chemistry-1) [1]. The structure and composition of ISC-1 are described in detail in [2]. The found chemical formula of the new zeolite ISC-1 is Na14K24Al38Si202O48 · nH2O. Further research on the principles of assembly of zeolites and prediction of another previously unknown zeolite, ISC-2 (Institute of Silicate Chemistry-2), and the conditions of its formation are presented in [3–5]. The combinatorial-topological analysis of the crystal structure of the new aluminosilicate zeolite ISC-1 with cubic cell parameters а = 25.039 Å, V = 15 699 Å3, and spatial group Im\(\bar {3}\)m is performed by computer-based methods (ToposPro software package) [6]. The topological type of the framework composed of bonded Т–(Si,Al)O4 tetrahedra is characterized by a combination of polyhedral tilings: t-grc (48 T-atoms), t-pau (32 T-atoms), t-plg (30 T-atoms),t-opr (16 T- atoms), and t-oto (16 T- atoms). A framework-forming precursor for zeolites of 30 T-tetrahedra, which corresponds to the t-plg tile and contains an organic template Me2-DABCO (N,N′-dimethyl-1,4-diazabicyclo[2.2.2]octane), is established by the complete decomposition of the 3D atomic lattice into cluster structures. t-plg nanoclusters with the symmetry g = \(\bar {3}\)m are characterized by 4-, 6-, and 8-rings and the n-hedral symbol [46. 62. 86]. Na-spacers statistically occupy neighboring positions in the 8-ring and between the 4‑rings of the neighboring t-plg clusters. The basic 3D lattice type indicative of t-plg clusters center-of-gravity positions correspond to a simple cubic lattice with CN = 6. The self-assembly code of the 3D structure from complementary bonded nanoclusters-precursors is simulated in its entirety: primary chain → microlayer → framework. The doubled distance between t-plg clusters centers corresponds to the cubic cell translation vector a = 25.039 Å.
Similar content being viewed by others
REFERENCES
Shevchenko, V.Y.;. and Krivovichev, S.V., Where are genes in paulingite? Mathematical principles of formation of inorganic materials on the atomic level, Struct. Chem., 2008, vol. 19, pp. 571–577.
Blatov, V.A., Ilyushin, G.D., Lapshin, A.E., and Golubeva, O.Y., Structure and chemical composition of the new zeolite ISC-1 from the data of nanocluster modeling, Glass Phys. Chem., 2010, vol. 36, pp. 663–672.
Shevchenko, V.Ya., Blatov, V.A., and Ilyushin, G.D., Combinatorial-topological modeling of the cluster self-assembly of crystal structures of zeolites of the GME, AFX, AFT, and ISC-2 family, Glass Phys. Chem., 2015, vol. 41, no. 5, pp. 443–452.
Ilyushin, G.D. and Blatov, V.A., Combinatorial and topological modeling of cluster self-assembly of the crystal structure of zeolites, Crystallogr. Rep., 2015, vol. 60, no. 4, pp. 453–465.
Shevchenko, V.Ya., Golov, A.A., Blatov, V.A., and Ilyushin, G.D., Combinatorial-topological modeling of the cluster self-assembly of zeolite crystal structures: computer search for molecular templates for new zeolite ISC-2, Russ. Chem. Bull., 2016, vol. 65, no. 1, pp. 29–39.
Lee, H., Shin, J., Choi, W., Choi, H.J., Yang, T., Zou, X., and Hong, S.B., PST-29: A missing member of the RHO family of embedded isoreticular zeolites, Chem. Mater., 2018, vol. 30, no. 19, pp. 6619–6623.
Blatov, V.A., Shevchenko, A.P., and Proserpio, D.M., Applied topological analysis of crystal structures with the program package ToposPro, Cryst. Growth Des., 2014, vol. 14, no. 7, pp. 3576–3585. http://topospro.com/.
Ilyushin, G.D., Modelirovanie protsessov samoorganizatsii v kristalloobrazuyushchikh sistemakh (Modeling of self-organization processes in crystal-forming systems), Moscow: Editorial URSS, 2003.
Ilyushin, G.D., Theory of cluster self-organization of crystal-forming systems. geometrical-topological modeling of nanocluster precursors with a hierarchical structure, Struct. Chem., 2012, vol. 20, no. 6, pp. 975–1043.
Pankova, A.A., Blatov, V.A., Ilyushin, G.D., and Proserpio, D.M., γ-Brass polyhedral core in intermetallisc: the nanocluster model, Inorg. Chem., 2013, vol. 52, no. 22, pp. 13 094–13 107.
Shevchenko, V.Ya., Blatov, V.A., and Ilyushin, G.D., Symmetry and topology codes of cluster self-assembly for icosahedral structures of the NaZn13-cF112 and TRB66-cF1944 family, Glass Phys. Chem., 2015, vol. 41, no. 4, pp. 341–351.
Shevchenko, V.Ya., Blatov, V.A., and Ilyushin, G.D., Modeling of self-organization processes in crystal-forming systems: symmetry and topological codes of cluster self-assembly of a 2D layered icosahedral structure of Sc18B238 (Pbam, oP514), Glass Phys. Chem., 2016, vol. 42, no. 3, pp. 221–229.
Shevchenko, V.Ya., Blatov, V.A., and Ilyushin, G.D., The symmetric and topological code of the cluster self-assembly of crystal structure ε-Mg23Al30 from nanoclusters K63 (1@12@50), Glass Phys. Chem., 2018, vol. 44, no. 6, in press.
Blatov, V.A., Ilyushin, G.D., and Proserpio, D.M., Nanocluster model of intermetallic compounds with giant unit cells: β, β'-Mg2Al3 polymorphs, Inorg. Chem., 2010, vol. 49, no. 4, pp. 1811–1818.
Shevchenko, V.Ya., Blatov, V.A., and Ilyushin, G.D., Intermetallic compounds of the NaCd2 family perceived as assemblies of nanoclusters, Struct. Chem., 2009, vol. 20, no. 6, pp. 975–982.
ACKNOWLEDGMENTS
This study was performed with the support of the Federal Agency for Scientific Organizations (FASO, agreement no. 007-GZ/Ch3363/26).
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated by D. Marinin
Rights and permissions
About this article
Cite this article
Shevchenko, V.Y., Blatov, V.A. & Ilyushin, G.D. Symmetrical and Topological Self-Assembly Code of the Crystalline Structure of a New Aluminosilicate Zeolite ISC-1 from Templated t-plg Suprapolyhedral Precursors. Glass Phys Chem 45, 85–90 (2019). https://doi.org/10.1134/S108765961902010X
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S108765961902010X