Abstract—
After several decades of study, the ordering structure existing in vitreous silica and the nature of silica glass transition remain controversial. This work describes a newly proposed nanoflake model for the medium range structure in vitreous silica and discusses the formation and evolution of the ordering structure in the glass transition process. The results show that there is a cooling rate independent critical temperature Tc corresponding to the formation of the ordering structure. This indicates that silica glass transition is a second-order phase transition.
Similar content being viewed by others
REFERENCES
Bragg, W.L., Atomic Structure of Minerals, Ithaka: Cornell Univ. Press, 1937, p. 89.
Anderson, P.W., Through a glass lightly, Science (Washington, DC, U.S.), 1995, vol. 267, p. 1615.
Debenedetti, P. G. and Stillinger, F. H., Supercooled liquids and the glass transition, Nature (London, U.K.), 2001, vol. 410, pp. 259–267.
McKenna, G.B., Diverging views on glass transition, Nat. Phys., 2008, vol. 4, pp. 673–674.
Zanotto, E.D. and Mauro, J.C., The glass state of matter: Its definition and ultimate fate, J. Non-Cryst. Solids, 2017, vol. 471, pp. 490–495.
Popov, A.I., What is glass? J. Non-Cryst. Solids, 2018, in press. https://doi.org/10.1016/j.jnoncrysol.2018.01.039.
Kalogeras, I.M. and Lobland, H.H., The nature of the glassy state: structure and glass transitions, J. Mater. Educ., 2012, vol. 34, pp. 69–94.
Lebedev, A.A., The polymorphism and annealing of glass, Tr. GOI, 1921, vol. 2, pp. 1–20.
Porai-Koshits, E.A., Golubkov, V.V., Titov, A.P., and Vasilevskaya, T.N., The microstructure of some glasses and melts, J. Non-Cryst. Solids, 1982, vol. 49, pp. 143–156.
Porai-Koshits, E.A., Genesis of concepts on structure of inorganic glasses, J. Non-Cryst. Solids, 1990, vol. 123, pp. 1–13.
Zachariasen, W.H., The atomic arrangement in glass, J. Am. Chem. Soc., 1932, vol. 54, pp. 3841–3851.
Warren, B.E., X-ray determination of the structure of glass, J. Am. Ceram. Soc., 1934, vol. 17, pp. 249–254.
Warren, B.E. and Biscoe, J., The structure of silica glass by X-ray diffraction studies, J. Am. Ceram. Soc., 1938, vol. 21, pp. 49–54.
Krivanek, O.L., Gaskell, P.H., and Howie, A., Seeing order in amorphous materials, Nature (London, U.K.), 1976, vol. 262, pp. 454–457.
Cheng, S., A nanoflake model for the medium range structure in vitreous silica, Phys. Chem. Glasses: Eur. J. Glass Sci. Technol. B, 2017, vol. 58, no. 2, pp. 33–40.
Wright, A.C., The great crystallite versus random network controversy: a personal perspective, Int. J. Appl. Glass Sci., 2014, vol. 5, no. 1, pp. 31–56.
Wright, A.C., The Cheng nanoflake model for the structure of vitreous silica: A critical appraisal, Phys. Chem. Glasses: Eur. J. Glass Sci. Technol. B, 2017, vol. 58, no. 5, pp. 226–228.
Cheng, S., Comments on “The Cheng nanoflake model for the structure of vitreous silica: a critical appraisal,” Phys. Chem. Glasses: Eur. J. Glass Sci. Technol. B, 2018, vol. 59, no. 2, pp. 114–117.
www.galleries.com/cristobalite.
Huang, P.Y., Kurasch, S., Srivastava, A., Skakalova, V., Kotakoski, J., Krasheninnikov, A.V., Hovden, R., Mao, Q., Meyer, J.C., Smet, J., Muller, D.A., and Kaiser, U., Direct imaging of two-dimensional silica glass on graphene, Nano Lett., 2012, vol. 12, pp. 1081–1086.
Hlavac, J., The Technology of Glass and Ceramics: An Introduction, Amsterdam: Elsevier Sci., 1983, p. 12.
Brazhkin, V.V., Lyapin, A.G., Popova, S.V. and Voloshin, R.N., New types of phase transitions: Phenomenology, concepts and terminology, in New Kinds of Phase Transitions: Transformations in Disordered Substances, Brazhkin, V.V., Buldyrev, S.V., Ryzhov, V.N. and Stanley, H.E., Eds., NATO ASI, Ser. II, Dordrecht: Kluwer Academic, 2002, vol. 81, pp. 15–27.
Schmelzer, W.P. and Gutzow I.S., Glasses and the Glass Transition, 1st ed., Weinheim: Wiley-VCH, 2011, p. 64.
Kittel, C., Introduction to Solid State Physics, 5th ed., New York: Wiley, 1976.
Skinner, L.B., Benmore, C.J., Weber, J.K.R., Wilding, M.C., Tumber, S.K., and Parise, J.B., A time resolved high energy X-ray diffraction study of cooling liquid SiO2, Phys. Chem. Chem. Phys., 2013, vol. 15, pp. 8566–8572.
Wright, A.C., Longer range order in single component network glasses? Phys. Chem. Glasses: Eur. J. Glass Sci. Technol. B, 2008, vol. 49, no. 3, pp. 103–107.
Elliott, S.R., Origin of the first sharp diffraction peak in the structure factor of covalent glasses, Phys. Rev. Lett., 1991, vol. 67, pp. 711–714.
Gaskell, P.H., Medium-range structure in glasses and low-Q structure in neutron and X-ray scattering data, J. Non-Cryst. Solids, 2005, vol. 351, pp. 1003–1013.
Forter, C.N. and Shockley, W., Order-disorder transitions in alloys, Rev. Mod. Phys., 1938, vol. 10, pp. 1–60.
Champagnon, B., Martinez, V., and Martinet, C., le Parc, R., and Levelut, C., Density and density fluctuations of SiO2 glass: Comparison and light-scattering study, Philos. Mag., 2007, vol. 87, pp. 691–695.
Cheng, C., Schiefelbein, S., Moore, L.L., Pierson-Stull, M., Sen, S., and Smith, C., Use of EELS to study the absorption edge of fused silica, J. Non-Cryst. Solids, 2006, vol. 352, pp. 3140–3146.
Cheng, C., The measurements of frozen-in disorder and thermal disorder of fused silica by EELS, Phys. Chem. Glasses: Eur. J. Glass Sci. Technol. B, 2009, vol. 50, no. 5, pp. 329–331.
Bruckner, R., Properties and structure of vitreous silica I, J. Non-Cryst. Solids, 1970, vol. 5, pp. 123–175.
Shelby, J.E., Density of vitreous silica, J. Non-Cryst. Solids, 2004, vol. 349, pp. 331–336.
Sen, S., Andrus, R.L., Baker, D.E., and Murtagh, M.T., Observation of an anomalous density minimum in vitreous silica, Phys. Rev. Lett., 2004, vol. 93, p. 125902.
FUNDING
This work was supported by the Office of Science, Office of Basic Energy Sciences, of the US Department of Energy under Contract no. DE-AC02-05CH11231.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Shangcong Cheng Medium Range Ordering Structure and Silica Glass Transition. Glass Phys Chem 45, 91–97 (2019). https://doi.org/10.1134/S1087659619020093
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1087659619020093