Abstract
A correlation was established between the character of the concentration dependence of the self-diffusion coefficients and the deviation from ideality for mixed alkali silicate glass and melts and a melt containing alkaline and alkaline-earth cations.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Borovskii, I.B., Gurov, K.P., Marchukova, I.D., and Ugaste, Yu.E., Protsessy vzaimnoi diffuzii v splavakh (Processes of Mutual Diffusion in Alloys), Moscow: Nauka, 1973.
Shinyaev, A.Ya., Diffuziya i vysokotemperaturnye svoistva splavov tugoplavkikh metallov (Diffusion and High Temperature Properties of Alloys of Refractory Metals), Moscow: Metallurgiya, 1982.
Sviridov, S.I., Diffusion of cations in sodium-potassium and sodium–barium silicate melts, Glass Phys. Chem., 2013, vol. 39, no. 2, pp. 130–135.
Zhabrev, V.A., Diffuzionnye protsessy v steklakh i stekloobrazuyushchikh rasplavakh (Diffusion Processes in Glasses and Glass-Forming Melts), St. Petersburg: Inst. Khim. Silikatov RAN, 1998.
Evstrop’ev, K.K., Ion diffusion and electroconductivity of glasses, Opt.-Mekh. Prom-st’, 1963, no. 5, pp. 38–41.
Wakabayashi, H. and Hayami, R., Ion exchange in Na2O–K2O–SiO2 glasses, in Proceedings of the10th International Congress on Glass, 1974, Kyoto, vol. 8, pp. 36–43.
McVay, G.L. and Day, D.E., Diffusion and internal friction in Na-Rb silicate glasses, J. Am. Ceram. Soc., 1970, vol. 53, no. 9, pp. 508–512.
Kolitsch, A., Richter, E., and Hinz, W., Untersuchung zur Ionenbeweglichkeit in einem Natrium-Kalium-Alumo-Silikatglas. I. Natrium und Kalium–Selbstdiffusion, Silikattechnik, 1980, vol. 31, no. 2, pp. 41–44.
Zhabrev, V.A., Moiseev, V.V., Nekrasov, A.A., and Sviridov, S.I., Study of the processes of mutual diffusion in sodium potassium silicate melts, Fiz. Khim. Stekla, 1978, vol. 4, no. 5, pp. 597–600.
Moiseev, V.V., Permyakova, T.V., Sheshukova, G.E., and Shul’ts, M.M., Thermodynamic characteristics of the ion exchange process in sodium silicate glasses, Fiz. Khim. Stekla, 1977, vol. 3, no. 1, pp. 22–28.
Kolitsch, A., Richter, E., and Hinz, W., Untersuchung zur Ionenbeweglichkeit in einem Natrium–Kalium–Alumo–Silikatglas. VII. Zur Einfluss von Druckspannungen auf den Interdiffusionkoeffizienten beim Kalium/Natrium-Austausch und zur Thermodynamik des K/Na Austausch in KNO3, Silikattechnik, 1980, vol. 31, no. 12, pp. 361–363.
Sviridov, S.I., Tyurnina, Z.G., Tyurnina, N.G., and Kurilenko, L.N., Ion exchange interaction of glassforming silicate melts with mixed melts of chlorides, Glass Phys. Chem., 2018, vol. 44, no. 2, pp. 85–91.
Sviridov, S.I., Tyurnina, Z.G., and Tyurnina, N.G., Enthalpies of mixing of two alkali glasses and glasses containing alkali and alkaline-earth cations, Glass Phys. Chem., 2008, vol. 34, no. 5, pp. 634–636.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © S.I. Sviridov, Z.G. Tyurnina, N.G. Tyurnina, 2018, published in Fizika i Khimiya Stekla.
Rights and permissions
About this article
Cite this article
Sviridov, S.I., Tyurnina, Z.G. & Tyurnina, N.G. Interrelation of Diffusion and Thermodynamic Characteristics in Silicate Glass and Glass-Forming Melts. Glass Phys Chem 44, 207–210 (2018). https://doi.org/10.1134/S108765961803015X
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S108765961803015X