Glass Physics and Chemistry

, Volume 44, Issue 2, pp 85–91 | Cite as

Ion-Exchange Interaction of Glass-Forming Silicate Melts with Mixed Chloride Melts

  • S. I. Sviridov
  • N. G. Tyurnina
  • Z. G. Tyurnina
  • L. N. Kurilenko


The ion-exchange interaction of the sodium aluminosilicate and sodium galliumsilicate melts with a mixture of molten Li, Na, K, Rb, Cs, and Ba chlorides is studied. It is established that two alkaline silicate melts are characterized by negative deviations from the ideal behavior, and silicate melts containing alkaline and alkaline-earth cations are characterized by noticeable positive deviations from the ideal behavior.


ion exchange silicate melts interchange energy deviation from ideal behavior 


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.


  1. 1.
    Takashi, K. and Yoshio, T., Heats of mixing in mixed alkali silicate glasses, J. Soc. Mater. Sci. Jpn., 1977, vol. 26, no. 287, pp. 785–790.CrossRefGoogle Scholar
  2. 2.
    Rogez, J. and Mathieu, J.-C., Entalpic de formation dans le systeme Na2O–K2O–SiO2, Phys. Chem. Liq., 1985, vol. 14, no. 14, pp. 259–271.CrossRefGoogle Scholar
  3. 3.
    Choudarv, U.V., Gaskell, D.R., and Belton, G.R., Thermodynamics of mixing in molten sodium-potassium silicates at 1100°C: the effect of a calcium oxide addition, Metal. Trans. B, 1977, vol. 8, no. 1, pp. 67–71.CrossRefGoogle Scholar
  4. 4.
    Kassis, N. and Friscliat, G.H., Dampfdrucke von Glasschmelzen des Mischalkalisystems Na2O–Rb2O–SiO2, Glastech. Ber., 1981, vol. 54, no. 4, pp. 89–98.Google Scholar
  5. 5.
    Garfinkel, H.T., Ion-exchange equlibria between glass and molten salts, J. Phys. Chem., 1968, vol. 72, no. 12, pp. 4175–4181.CrossRefGoogle Scholar
  6. 6.
    Lezzi, P.J. and Tomozawa, M., Enthalpy of mixing of mixed alkali glasses, J. Non-Cryst. Solids, 2010, vol. 356, nos. 28–30, pp. 1439–1446.CrossRefGoogle Scholar
  7. 7.
    Sviridov, S.I., Tyurnina, Z.G., and Tyurnina, N.G., Enthalpies of mixing of two alkali glasses and glasses containing alkali and alkaline-earth cations, Glass Phys. Chem., 2008, vol. 34, no. 5, pp. 634–636.CrossRefGoogle Scholar
  8. 8.
    Zhabrev, V.A., Moiseev, V.V., Nekrasov, A.A., and Sviridov, S.I., Study of interdiffusion processes in sodium potassium silicate melts, Fiz. Khim. Stekla, 1978, vol. 4, no. 5, pp. 597–599.Google Scholar
  9. 9.
    Moiseev, V.V., Permyakova, T.V., Sheshukova, G.E., and Shul’ts, M.M., Thermodynamical characteristics of ion exchange process in sodium silicate glasses, Fiz. Khim. Stekla, 1977, vol. 3, no. 1, pp. 22–28.Google Scholar
  10. 10.
    Gerasimov, Ya.I. and Geiderikh, V.A., Termodinamika rastvorov (Thermodynamics of Solutions), Moscow: Mosk. Gos. Univ., 1980.Google Scholar
  11. 11.
    Lamsden, J., Thermodynamics of molten mixtures of alklimetall halides, Discuss. Faraday Soc., 1961, no. 32, pp. 138–146.CrossRefGoogle Scholar
  12. 12.
    Egan, J.J. and Bracker, J., Thermodynamic properties of some binary fused chloride mixtures obtained from e.m.f. measurements, J. Chem. Thermodyn., 1974, vol. 6, no. 1, pp. 9–16.CrossRefGoogle Scholar
  13. 13.
    Huheey, J.E., Inorganic Chemistry: Principles of Structure and Reactivity, New York: Harper Collins College Publ., 1993.Google Scholar
  14. 14.
    Diagrammy sostoyaniya sistem tugoplavkikh oksidov (State Diagrams of Refractory Oxide Systems), Galakhov, F.Ya., Ed., Leningrad: Nauka, 1985, vol. 5, part 1.Google Scholar
  15. 15.
    Mazurin, O.V, Roskova, G.P., Aver’yanov, V.I., and Antropova, T.V., in Dvukhfaznye stekla: struktura, svoistva, primenenie (Two-Phase Glasses: Structure, Properties, Application), Varshal, B.G., Ed., Leningrad: Nauka, 1991.Google Scholar
  16. 16.
    Vedishcheva, N.M. and Wright, A.C., The thermodynamic origin of compositional nanoheterogeneity in glasses, Phys. Chem. Glasses: Eur. J. Glass Sci. Technol., Part B, 2017, vol. 58, no. 4, pp. 150–155.Google Scholar
  17. 17.
    Vedishcheva N.M., Wright A.C. Chemical structure of oxide glasses: a concept for establishing structure-property relationships, in Glass. Selected Properties and Crystallization, Schmelzer J.W.P., Ed., Berlin: De Gruyter, 2014, Chap. 5, pp. 269–299.Google Scholar
  18. 18.
    Vedishcheva, N.M., Shakhmatkin, B.A., and Wright, A.C., Thermodynamic modelling of the structure and properties of glasses in the systems Na2O–B2O3–SiO2 and Na2O–CaO–SiO2, Phys. Chem. Glasses, 2005, vol. 46, no. 2, pp. 99–107.Google Scholar
  19. 19.
    Neudorf, D.A. and Elliott, J.F., Thermodynamic properties of Na2O–SiO2–CaO melts at 1000 to 1100°C, Metall. Trans. B, 1980, vol. 11, no. 12, pp. 607–614.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • S. I. Sviridov
    • 1
  • N. G. Tyurnina
    • 1
  • Z. G. Tyurnina
    • 1
  • L. N. Kurilenko
    • 1
  1. 1.Grebenshchikov Institute of Silicate ChemistryRussian Academy of SciencesSt. PetersburgRussia

Personalised recommendations