Skip to main content
Log in

Development of Approaches for Designing and Preparing Magnetic Nanocomposites Based on Zeolite Beta and Magnetite Nanoparticles under Hydrothermal Conditions

  • Published:
Glass Physics and Chemistry Aims and scope Submit manuscript

Abstract

Nanocomposites based on zeolite Beta and magnetite nanoparticles (MNs) are obtained under hydrothermal conditions. Nanoparticles synthesized under various conditions and having different surface properties are added at the preparatory stage of a zeolite Beta gel that is then subjected to hydrothermal treatment at 140°C for 48 h. It is found that modifying the surface of the nanoparticles by a cationic polymer, polydiallyldimethylammonium chloride (PDDAC) makes it possible to significantly increase the amount of magnetite introduced into the zeolite structure (up to 40 wt % compared to 2–10 wt % for unmodified particles) and obtain zeolites with a magnetic core that contain nanoparticles within the zeolite structure. It is shown that doping the initial gels with MNs allows obtaining magnetically sensitive zeolites with particles of 100 to 200 nm, which are 200 nm smaller than the zeolite particles obtained under the same conditions without doping.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Arruebo, M., Drug delivery from structured porous inorganic materials, WIREs Nanomed. Nanobiotechnol., 2012, vol. 4, no. 1, pp. 16–30.

    Article  Google Scholar 

  2. Ahuja, G. and Patak, K., Porous carriers for controlled/modulated drug delivery, Indian J. Pharm. Sci., 2009, vol. 71, no. 6, pp. 599–607.

    Article  Google Scholar 

  3. Sağir, T., Huysal, M., Durmus, Z., Kurt, B.Z., and Senel, M., Preparation and in vitro evaluation of 5-flourouracil loaded magnetite-zeolite nanocomposite (5-FU-MZNC) for cancer drug delivery, Biomed. Pharmacother., 2016, vol. 77, pp. 182–190.

    Article  Google Scholar 

  4. Cao, J., Liu, X.-W., Fu, R., and Tan, X.-Y., Magnetic P zeolites: Synthesis, characterization and behavior in potassium extraction from seawater, Sep. Purif. Technol., 2008, vol. 63, no. 1, pp. 92–100.

    Article  Google Scholar 

  5. Cao, J., Guihuan, C., Hongfei, G., and Jianxin, C., Synthesis and characterization of magnetic ZSM-5 zeolite, Trans. Tianjin. Univ., 2013, vol. 19, pp. 326–331.

    Article  Google Scholar 

  6. Belikov, V.G. and Kuregyan, A.G., Generation and medicobiological application of magnetic fields and carriers (review), Pharm.-Chem. J., 2001, vol. 35, no. 2, pp. 88–95.

    Article  Google Scholar 

  7. Brusnetsov, N.A., Baiburtskii, F.S., and Tarasov, V.V., Production technology and application of polyfunctional magnetically guided superparamagnetic preparations (a review), Pharm.-Chem. J., 2002, vol. 36, no. 4, pp. 197–205.

    Article  Google Scholar 

  8. Ismailova, K.G., Efremenko, V.I., and Kuregyan, A.G., Biotechnology of magnet-driven liposome preparations, Pharm.-Chem. J., 2005, vol. 39, no. 7, pp. 385–387.

    Article  Google Scholar 

  9. Galanov, A.I., Yurmazova, T.A., Savel’ev, G.G., Buldakov, M.A., Rudyk, Yu.V., Litvyakov, N.V., Nechaev, K.A., Tuzikov, S.V., Cherdyntseva, N.V., and Yavorovskii, N.A., Development of magnetic nanostructured iron-based materials as potential vectors for drug-delivery application, Sib. Onkol. Zh., 2008, vol. 27, no. 3, pp. 50–57.

    Google Scholar 

  10. Lima, T.M., Lima, C.G.S., Rathi, A.K., Gawande, M.B., Tucek, J., Urquieta-Gonzalea, E.A., Zbořil, R., Paixāo, M.W., and Varma, R.S., Magnetic ZSM-5 zeolite: a selective catalyst for the valorization of furfurylalcohol to γ-valerolactone, alkyl levulinates or levulinic acid, Green Chem., 2016, vol. 18, no. 20, pp. 5586–5593.

    Article  Google Scholar 

  11. Deng, B.Y., Deng, C., Qi, D., Liu, C., Liu, J., Zhang, X., and Zhao, D., Synthesis of core/shell colloidal magnetic zeolite microsphere for the immobilization of trypsin, Adv. Mater., 2009, vol. 21, no. 13, pp. 1377–1382.

    Article  Google Scholar 

  12. Pasti, L., Sarti, E., Cavazzini, A., Marchetti, N., Dondi, F., and Martucci, A., Factors affecting drug adsorption on beta zeolites, J. Sep. Sci., 2013, vol. 36, nos. 9–10, pp. 1604–1611.

    Article  Google Scholar 

  13. Golubeva, O.Yu. and Ul’yanova, N.Yu., Stabilization of silver nanoparticles and clusters in porous zeolite matrices with Rho, Beta, and Paulingite structures, Glass Phys. Chem., 2015, vol. 41, no. 5, pp. 537–544.

    Article  Google Scholar 

  14. Brazovskaya, E.Yu. and Golubeva, O.Yu., Study of the effect of isomorphic substitutions in the framework of zeolites with a beta structure on their porosity and sorption characteristics, Glass Phys. Chem., 2017, vol. 43, no. 4, pp. 357–362.

    Article  Google Scholar 

  15. Bárcia, P.S., Silva, J.A.C., and Rodrigues, A.E., Multicomponent sorption of hexane isomers in zeolite beta, AIChE J., 2007, vol. 53, no. 8, pp. 1970–1981.

    Article  Google Scholar 

  16. Kuwakara, Y., Miyazaki, T., Shirosaki, Y., and Kawashita, M., Effects of organic polymer addition in magnetite synthesis on the crystalline structure, RSC Adv., 2014, vol. 4, pp. 23359–23363.

    Article  Google Scholar 

  17. Guo, S., Li, D., Zhang, L., Jing, L., and Wang, E., Monodisperse mesoporous superparamagnetic singlecrystal magnetite nanoparticles for drug delivery, Biomaterials, 2009, vol. 30, no. 10, pp. 1881–1889.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to O. Yu. Golubeva.

Additional information

Original Russian Text © O.Yu. Golubeva, E.Yu. Brazovskaya, N.Yu. Ul’yanova, Yu.A. Morozova, 2018, published in Fizika i Khimiya Stekla.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Golubeva, O.Y., Brazovskaya, E.Y., Ul’yanova, N.Y. et al. Development of Approaches for Designing and Preparing Magnetic Nanocomposites Based on Zeolite Beta and Magnetite Nanoparticles under Hydrothermal Conditions. Glass Phys Chem 44, 108–114 (2018). https://doi.org/10.1134/S1087659618020049

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1087659618020049

Keywords

Navigation