Skip to main content
Log in

Preparation of antireflection coatings from silicon dioxide on glass and quartz by the sol-gel method with oligoethers

  • Published:
Glass Physics and Chemistry Aims and scope Submit manuscript

Abstract

Antireflection coatings with a low refractive index (1.18–1.23) have been prepared on silicate glass and optical quartz from mesoporous silicon dioxide synthesized by the sol-gel method in the presence of oligoethers. The optimum concentration of the oligoester in the sol is equal to 1.5–2.5 wt %. For the single-layer double-sided coating, the maximum transmission is equal to 99.0% for the silicate glass and 99.9% for quartz.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Macleod, H.A., Thin Film Optical Filters, Bristol: Adam Hilger, 1986.

    Book  Google Scholar 

  2. Suikovskaya, N.V., Khimicheskie metody polucheniya tonkikh prozrachnykh plenok (Chemical Methods for Producing Thin Transparent Films), Leningrad: Khimiya, 1971 [in Russian].

    Google Scholar 

  3. Nikolaeva, L.V. and Borisenko, A.I., Tonkosloinye stekloemalevye i steklokeramicheskie pokrytiya (Thin-Layer Glass-Enamel and Glass-Ceramic Coatings), Leningrad: Nauka, 1980 [in Russian].

    Google Scholar 

  4. Movchan, T.G., Khamova, T.V., Shilova, O.A., Tarasyuk, E.V., Potapov, A.N., Ur’ev, N.B., Klimenko, N.S., and Shevchenko, V.V., Kinetics of Structuring in the Sol-Gel Systems Based on Tetraethoxysilane with Organic Additives: II. Gels, Fiz. Khim. Stekla, 2006, vol. 32, no. 6, pp. 916–925 [Glass Phys. Chem. (Engl. transl.), 2006, vol. 32, no. 6, pp. 666–673].

    Google Scholar 

  5. Kresge, C.T., Leonowicz, M.E., Roth, W.J., Vartuli, J.C., and Beck, J.S., Ordered Mesoporous Molecular Sieves Synthesized by a Liquid-Crystal Template, Nature (London), 1992, vol. 359, pp. 710–712.

    Article  CAS  ADS  Google Scholar 

  6. Wan, Y. and Zhao, D., On the Controllable Soft-Templating Approach to Mesoporous Silicates, Chem. Rev., 2007, vol. 107, no. 7, pp. 2821–2860.

    Article  CAS  PubMed  Google Scholar 

  7. Lu, Y., Ganguli, R., Drewien, C.A., Anderson, M.T., Brinker, C.J., Gong, W., Guo, Y., Soyez, H., Dunn, B., Huang, M.H., and Zink, J.I., Continuous Formation of Supported Cubic and Hexagonal Mesoporous Films by Sol-Gel Dip-Coating, Nature (London), 1997, vol. 389, pp. 364–368.

    Article  CAS  ADS  Google Scholar 

  8. Fujita, S. and Inagaki, S., Self-Organization of Organosilica Solids with Molecular-Scale and Mesoscale Periodicities, Chem. Mater., 2008, vol. 20, no. 3, pp. 891–908.

    Article  CAS  Google Scholar 

  9. Lee, D., Yu, C., and Lee, K., Study on Hydrothermal Stability and Catalytic Activity of Nanosphere-Walled Mesoporous Silica, J. Phys. Chem., 2008, vol. 112, no. 13, pp. 5136–5140.

    CAS  Google Scholar 

  10. Troitskii, B.B., Babin, A.A., Lopatin, M.A., Mamaev, Yu.A., Denisova, V.N., Novikova, M.A., and Khokhlova, L.V., To the Problem of Self-Assembly of Mixtures of Inorganic and Organic Phases under the Sol-Gel Process Conditions, Izv. Akad. Nauk, Ser. Khim., 2008, no. 12, pp. 2406–2409 [Russ. Chem. Bull. (Engl. transl.), 2008, vol. 57, no. 12, pp. 2456–2459].

  11. Troitskii, B.B., Babin, A.A., Lopatin, M.A., Denisova, V.N., Novikova, M.A., Mamaev, Yu.A., and Khokhlova, L.V., A Technique for Preparing Thin Antireflection Coatings Based on Mesoporous Silicon Dioxide by Sol-Gel Method in the Presence of Organic Acids, Functional Derivatives of Organic Acids, and Esters of Organic Acids, RF Patent 2368575, Byull. Izobret., 2009, no. 27.

  12. Troitskii, B.B., Denisova, V.N, Novikova, M.A., Lopatin, M.A., Khokhlova, L.V., and Golubev, A.E., Deposition of Thin Antireflection Coatings Based on Mesoporous Silicon Dioxide by the Sol-Gel Method in the Presence of Carbochain Polymers and Statistical Copolymers, Zh. Prikl. Khim. (St. Petersburg), 2008, vol. 81, no. 8, pp. 1365–1369 [Russ. J. Appl. Chem. (Engl. Transl.), vol. 81, no. 8, pp. 1441–1445].

    Google Scholar 

  13. Troitskii, B.B., Lopatin, M.A., Denisova, V.N., Novikova, M.A., and Khokhlova, L.V., A Technique for Preparing Thin Antireflection Coatings Based on Mesoporous Silicon Dioxide by Sol-Gel Method in the Presence of Some Polymers and Statistical Copolymers, RF Patent 2371399, Byull. Izobret., 2009, no. 30.

  14. Troitskii, B.B., Lopatina, T.I., Denisova, V.N., Novikova, M.A., and Khokhlova, L.V., A Technique for Preparing Thin Antireflection Coatings Based on Mesoporous Silicon Dioxide by Sol-Gel Method in the Presence of Ethylene Oxide Oligomers and Propylene Oxide Oligomers, RF Patent 2368576, Byull. Izobret., 2009, no. 27.

  15. Masuda, J., Takano, A., Suzuki, J., Nagata, Y., Noro, A., Hayashida, K., and Matsushita, Y., Composition-Dependent Morphological Transition of Hierarchically-Ordered Structures Formed by Multiblock Terpolymers, Macromolecules, 2007, vol. 40, no. 11, pp. 4023–4027.

    Article  CAS  ADS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to B. B. Troitskii.

Additional information

Original Russian Text © B.B. Troitskii, Yu.A. Mamaev, A.A. Babin, M.A. Lopatin, V.N. Denisova, M.A. Novikova, L.V. Khokhlova, T.I. Lopatina, 2010, published in Fizika i Khimiya Stekla.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Troitskii, B.B., Mamaev, Y.A., Babin, A.A. et al. Preparation of antireflection coatings from silicon dioxide on glass and quartz by the sol-gel method with oligoethers. Glass Phys Chem 36, 609–616 (2010). https://doi.org/10.1134/S108765961005010X

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S108765961005010X

Key words

Navigation