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Kizilcaören ore-bearing complex with carbonatites (northwestern Anatolia, Turkey): Formation time and mineralogy of rocks

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Abstract

The results of isotope-geochronological and mineralogical studies of the rocks making up the Kizilcaören fluorite-barite-REE deposit, northwestern Anatolia, Turkey are discussed in the paper. The ore is a constituent of the subvolcanic complex localized in a large fault zone. The complex combines (from earlier to later rocks): (1) phonolite and trachyte stocks, (2) carbonatite and carbonate-silicate dikelike bodies; and (3) fluorite-barite-bastnaesite ore in the form of thick homogeneous veins and cement in breccia. The K-Ar dating of silicate igneous rocks and carbonatites shows that they were formed in the Chattian Age of the Oligocene 25–24 Ma ago. Mineralogical observations show that the ore is the youngest constituent in the rock complex. Supergene alteration deeply transformed ore-bearing rocks, in particular, resulting in leaching of primary minerals, presumably Ca-Mn-Fe carbonates, and in cementation of the residual bastnaesitefluorite framework by Fe and Mn hydroxides. Most of the studied rocks contain pyrochlore, LREE fluorocarbonates, Nb-bearing rutile, Fe-Mg micas, and K-feldspar. The genetic features of the deposit have been considered. In general, the ore-bearing rock complex is compared in the set of rocks and their mineralogy and geochemistry with deposits of the Gallinas Mountains in the United States, the Arshan and Khalyuta deposits in the western Transbaikalia region, and Mushugai-Khuduk deposit in Mongolia. The Kizilcaören deposit represents a variant of postmagmatic mineralization closely related to carbonatite magmatism associated with alkaline and subalkaline intermediate rocks.

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References

  • Altuncu, S., Comparative investigation of fluoride deposits in Turkey, Ph.D. Thesis, Istanbul: Istanbul Univesity, 2009.

    Google Scholar 

  • Andreev, G.V., Geology and mineralogy of ore at the Apatitovoe deposit, the Mushugai ore cluster, Mongolia, Otech. Geol., 1995, no. 10, pp. 39–44.

    Google Scholar 

  • Andreeva, I.A., Naumov, V.B., Kovalenko, V.I., and Kononkova, N.N., Fluoride-sulfate and chloride-sulfate salt melts of the carbonatite-bearing complex Mushugai Khuduk, southern Mongolia, Petrology, 1998, vol. 6, no. 3, pp. 284–292.

    Google Scholar 

  • Andreeva, I.A., Naumov, V.B., Kovalenko, V.I., and Kononkova, N.N., The magma composition and genesis of theralite from the Mushugai Khuduk carbonatite-bearing complex in southern Mongolia, Geochem. Int., 1999, vol. 37, no. 8, pp. 735–749.

    Google Scholar 

  • Bolonin, A.V., Nikiforov, A.V., Lykhin, D.A., and Sugorakova, A.M., The Chailag-Khem fluorite-barium-strontium rare earth carbonatite occurrence, the Western Sayan Range, Russia, Geol. Ore Deposits, 2009, vol. 51, no. 1, pp. 17–32.

    Article  Google Scholar 

  • Borodin, L.S. and Nazarenko, I.I., Chemical composition of pyrochlore and isomorp[hic replacements in A2B2X7 molecule, Geokhimiya, 1957, no. 4, pp. 278–295.

    Google Scholar 

  • Delaloye, M. and Özgenç, I., Petrography and age determinations of the alkaline volcanic rocks and carbonatite of Kızılcaören district, Beylikahır-Eski ehir, Turkey, Schweiz. Min. Petrogr., 1983, vol. 63, pp. 289–294.

    Google Scholar 

  • Dilek, Y. and Altunkaynak, S., Geochemical and temporal evolution of Cenozoic magmatism in western Turkey: mantle response to collision, slab break-off, and lithospheric tearing in an orogenic belt, Geol. Soc. London Spec. Publ., 2009, vol. 311, pp. 631–655.

    Article  Google Scholar 

  • Dilek, Y. and Altunkaynak, S., Geochemistry of Neogene-Quaternary alkaline volcanism in western Anatolia, Turkey, and implications for the Aegean mantle, Int. Geol. Rev., 2010, vol. 52, pp. 631–655.

    Article  Google Scholar 

  • Doroshkevich, A.G., Ripp, G.S., Viladkar, S.G., and Vladykin, N.V., The Arshan REE carbonatites, southwestern Transbaikalia: mineralogy, paragenesis, and evolution, Can. Mineral., 2008, vol. 46, pp. 807–823.

    Article  Google Scholar 

  • Gültekin A.H., Örgün Y., and Suner, F., Geology, mineralogy and fluid inclusion data of the Kizilcaören fluoritebarite-REE deposit, Eskisehir, Turkey, J. Asian Earth Sci., 2003, vol. 21, pp. 365–376.

    Article  Google Scholar 

  • Hatzl, T. and Morteani, G., The hydrothermal formation of bastnaesite and fluocerite by decarbonatization of calciocarbonatites at high HF-fugacity at Kizilçaören (Turkey), in Rare Earth Minerals: Chemistry, Origin and Ore deposits, London: Natural History Museum, 1993, pp. 47–49.

    Google Scholar 

  • Moix, P. and Beccaletto, L., Kozur H. W. et al., A new classification of the Turkish terranes and sutures and its implication for the paleotectonic history of the region, Tectonophysics, 2008, vol. 451, pp. 7–39.

    Article  Google Scholar 

  • Nikiforov, A.V., Bolonin, A.V., Sugorakova, A.M., et al., Carbonatites of central Tuva: Geological structure and mineral and chemical composition, Geol. Ore Deposits, 2005, vol. 47, no. 4, pp. 326–345.

    Google Scholar 

  • Nikiforov, A.V., Bolonin, A.V., Pokrovsky, B.G., et al., Isotope geochemistry (O, C, S, Sr) and Rb-Sr age of carbonatites in central Tuva, Geol. Ore Deposits, 2006, vol. 48, no. 4, pp. 256–276.

    Article  Google Scholar 

  • Okay, A.I., Harris, N.B.W., and Kelley, S.P., Exhumation of blueschists along a Tethyan suture in Northwest Turkey, Tectonophysics, 1998, vol. 285, pp. 275–299.

    Article  Google Scholar 

  • Nikiforov, A.V., Yarmolyuk, V.V., Kovalenko, V.I., et al., Late Mesozoic carbonatites of western Transbaikalia: Isotopic-geochemical characteristics and sources, Petrology, 2002, vol. 10, no. 2, pp. 146–164.

    Google Scholar 

  • Özgenç I., Geology and REE-geochemistry of carbothermal bastnaesite-fluorite-barite deposit of Kızılcaören (Sivrihisar, Eski ehir), Geol. Bull. Turkey, 1993, vol. 36, pp. 1–11.

    Google Scholar 

  • Panina, L.I. and Motorina, I.V., Liquid immiscibility in deep-seated magmas and the generation of carbonatite melts, Geochem. Int., 2008, vol. 46, no. 5, pp. 448–464.

    Article  Google Scholar 

  • Perhac, R.M. and Heinrich, E.W., Fluorite-bastnaesite deposits of the Gallinas Mountains, New Mexico and bastnaesite paragenesis, Econ. Geol., 1964, vol. 59, pp. 226–239.

    Article  Google Scholar 

  • Proskurnin, V.F., Petrov, O.V., Gavrish, A.V., et al., Early Mesozoic carbonatite belt in Taimyr Peninsula, Litosfera, 2010, no. 3, pp. 95–102.

    Google Scholar 

  • Samoilov, V.S. and Kovalenko, V.I., Kompleksy shchelochnykh porod i karbonatitov Mongolii (Complexes of Alkaline Rocks and Carbonatites in Mongolia), Moscow: Nauka, 1983.

    Google Scholar 

  • Santfakıoğlu, E., Özen, H., and Hall, C., Petrogenesis of extension-related alkaline volcanism in Karaburhan (Sivrihisar-Eskisehir), NW Anatolia, Turkey, J. Asian Earth Sci., 2009, vol. 35, pp. 502–515.

    Article  Google Scholar 

  • Sherlock, S., Kelley, S.P., Inger, S., Harris, N., and Okay, A.I., 40Ar-39Ar and Rb-Sr geochronology of high-pressure metamorphism and exhumation history of the Tav anli Zone, NW Turkey, Contrib. Mineral. Petrol., 1999, vol. 137, pp. 46–58.

    Google Scholar 

  • Steiger, R.H. and Jager, E., Subcomission on Geochronology: Convention on the use of decay constants in geo- and cosmochronology, Earth Planet. Sci. Lett., 1977, no. 36, pp. 359–362.

    Google Scholar 

  • Stumpfl, E.F., Kırıkoğlu M.S. Fluorite-barite-rare earth deposit at Kızılcaören, Turkey, Mitt. Osterr. Ges., 1986, vol. 78, pp. 193–200.

    Google Scholar 

  • Tucker, R.D., Belkin, H.E., Schulz, K.J., et al., A major light rare-earth element (LREE) resource in the Khanneshin carbonatite complex, southern Afghanistan, Econ. Geol., 2012, vol. 107, pp. 197–208.

    Article  Google Scholar 

  • Williams-Jones, A.E., Samson, I.M., and Olivo, G.R., The genesis of hydrothermal fluorite-REE deposits in the Gallinas Mountains, New Mexico, Econ. Geol., 2000, vol. 95, no. 2, pp. 327–341.

    Article  Google Scholar 

  • Woolley, A.R., Alkaline Rocks and Carbonatites of the World, Part 3: Africa, London: Geol. Society London, 2001.

    Google Scholar 

  • Yarmolyuk, V.V. and Ivanov, V.G., Late Mesozoic and Cenozoic magmatism and geodynamics of western Transbaikalia, Geotectonics, 2000, vol. 34, no. 2, pp. 121–140.

    Google Scholar 

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Correspondence to A. V. Nikiforov.

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Original Russian Text © A.V. Nikiforov, H. Öztürk, S. Altuncu, V.A. Lebedev, 2014, published in Geologiya Rudnykh Mestorozhdenii, 2014, Vol. 56, No. 1, pp. 41–69.

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Nikiforov, A.V., Öztürk, H., Altuncu, S. et al. Kizilcaören ore-bearing complex with carbonatites (northwestern Anatolia, Turkey): Formation time and mineralogy of rocks. Geol. Ore Deposits 56, 35–60 (2014). https://doi.org/10.1134/S107570151401005X

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