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New Reactions of Tropylium Salts with 4-Nitrobenzohydrazide, Semicarbazide, Thiosemicarbazide, and N-Benzylurea

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Abstract

Reactions of tropylium tetrafluoroborate with 4-nitrobenzohydrazide, semicarbazide hydrochloride, thiosemicarbazide, and N-benzylurea afforded the corresponding mono- and/or ditropyl derivatives, N′-(cyclohepta-2,4,6-trien-1-yl)-4-nitrobenzohydrazide, N′,N′-di(cyclohepta-2,4,6-trien-1-yl)-4-nitrobenzohydrazide, 2,2-di(cyclohepta-2,4,6-trien-1-yl)hydrazine-1-carboxamide, N-2-di(cyclohepta-2,4,6-trien-1-yl)hydrazinecarbothioamide, and N-benzyl-3-(cyclohepta-2,4,6-trien-1-yl)urea, as potential biologically active compounds.

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REFERENCES

  1. Yunnikova, L.P. and Akent’eva, T.A., RU Patent no. 2479571 C1, 2013; Byull. Izobret., 2013, no. 11.

  2. Yunnikova, L.P., Akent’eva, T.A., and Ésenbaeva, V.V., Pharm. Chem. J., 2015, vol. 49, p. 243. https://doi.org/10.1007/s11094-015-1263-3

    Article  CAS  Google Scholar 

  3. Yunnikova, L.P., Likhareva, Y.E., and Akent’eva, T.A., Russ. J. Gen. Chem., 2017, vol. 87, p. 347. https://doi.org/10.1134/S1070363217020323

    Article  CAS  Google Scholar 

  4. Yunnikova, L.P. and Esenbaeva, V.V., Russ. J. Org. Chem., 2018, vol. 54, p. 1018. https://doi.org/10.1134/S1070428018070084

    Article  CAS  Google Scholar 

  5. Yunnikova, L.P., Esenbaeva, V.V., and Shklyaeva, E.V., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 2018, vol. 61, p. 47. https://doi.org/10.6060/ivkkt.20186108.5817

    Article  CAS  Google Scholar 

  6. Esenbaeva, V.V., Yunnikova, L.P., Kudayarova, T.V., and Danilova, E.A., Russ. J. Gen. Chem., 2018, vol. 88, p. 2691. https://doi.org/10.1134/S0044460X18120235

    Article  CAS  Google Scholar 

  7. Esenbaeva, V.V. and Yunnikova, L.P., Russ. J. Gen. Chem., 2018, vol. 88, p. 829. https://doi.org/10.1134/S107036321804031X

    Article  CAS  Google Scholar 

  8. Chandrasekhar, T., Kumar, L.V., Reddy, A.B., Naik, P.J., and Swamy, G.N., Chem. Pharm. Res., 2012, vol. 4, p. 2795.

    CAS  Google Scholar 

  9. Sriram, D., Yogeeswazy, P., Thirumurugan, R., and Pavana, R.K., J. Med. Chem., 2006, vol. 49, p. 3448. https://doi.org/10.1021/jm060339h

    Article  CAS  PubMed  Google Scholar 

  10. Gate, L. and Tew, K.D., Cancer Management in Man: Chemotherapy, Biological Therapy, Hyperthermia and Supporting Measures, Minev, B., Dordrecht: Springer, 2011, vol. 13, p. 61.

  11. Beauchesne, P., Cancers, 2012, vol. 4, p. 77. https://doi.org/10.3390/cancers4010077

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  12. Nikolaeva, L.L., Lantsova, A.V., Saranova, E.V., Polozkova, A.P., Orlova, O.L., Oborotova, N.A., Musiyak, V.V., Levit, G.L., Krasnov, V.P., and Bunyatyan, N.D., Ross. Bioter. Zh., 2015, vol. 14, p. 113.

    Google Scholar 

  13. Gazieva, G.A., Struchkova, M.I., and Kolotyrkina, N.G., Chem. Heterocycl. Compd., 2011, vol. 47, p. 210. https://doi.org/10.1007/s10593-011-0742-z

    Article  CAS  Google Scholar 

  14. CrysAlisPro, Agilent Technologies, Version 1.171.37.33 (release 27-03-2014 CrysAlis171 .NET).

  15. Dolomanov, O.V., Bourhis, L.J., Gildea, R.J., Howard, J.A.K., and Puschmann, H., J. Appl. Crystallogr., 2009, vol. 42, p. 339. https://doi.org/10.1107/S0021889808042726

    Article  CAS  Google Scholar 

  16. Sheldrick, G.M., Acta Crystallogr., Sect. A, 2008, vol. 64, p. 112. https://doi.org/10.1107/S0108767307043930

    Article  CAS  PubMed  Google Scholar 

  17. Sheldrick, G.M., Acta Crystallogr., Sect. C, 2015, vol. 71, p. 3. https://doi.org/10.1107/S2053229614024218

    Article  CAS  Google Scholar 

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Funding

This study was performed under financial support by the Russian Foundation for Basic Research (project no. 19-03-00888).

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Authors and Affiliations

  1. Pryanishnikov Perm State Agrarian Technological University, 614990, Perm, Russia

    L. P. Yunnikova, T. A. Akentʼeva & Yu. E. Likhareva

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  1. L. P. Yunnikova
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  2. T. A. Akentʼeva
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  3. Yu. E. Likhareva
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Correspondence to L. P. Yunnikova.

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Yunnikova, L.P., Akentʼeva, T.A. & Likhareva, Y.E. New Reactions of Tropylium Salts with 4-Nitrobenzohydrazide, Semicarbazide, Thiosemicarbazide, and N-Benzylurea. Russ J Org Chem 56, 2244–2247 (2020). https://doi.org/10.1134/S1070428020120313

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