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New Tetracyclic Spiro-1,2,4-trioxolanes (Ozonides). Synthesis and Mass Spectrometric Study

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Abstract

New tetracyclic dispiro-1,2,4-trioxolanes (ozonides) were synthesized by reactions of 5–7-membered alicyclic 1,5-diketones with 30% hydrogen peroxide in diethyl ether or ethanol in the presence of boron trifluoride-diethyl ether complex or a strong mineral acid (HCl, H2SO4, HClO4). Mass spectrometric study of the title compounds under atmospheric pressure chemical ionization revealed specificity of fragment ion decomposition with respect to the ring size, which makes it possible to identify such compounds by their mass spectra.

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Authors and Affiliations

  1. Far Eastern Federal University, ul. Sukhanova 8, Vladivostok, 690091, Russia

    T. I. Akimova & O. A. Soldatkina

  2. Zhirmunskii Institute of Marine Biology, Far Eastern Branch, Russian Academy of Sciences, ul. Pal’chevskogo 17, Vladivostok, 690041, Russia

    V. G. Rybin

Authors
  1. T. I. Akimova
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  2. V. G. Rybin
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  3. O. A. Soldatkina
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Correspondence to T. I. Akimova.

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Deceased.

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Akimova, T.I., Rybin, V.G. & Soldatkina, O.A. New Tetracyclic Spiro-1,2,4-trioxolanes (Ozonides). Synthesis and Mass Spectrometric Study. Russ J Org Chem 55, 101–107 (2019). https://doi.org/10.1134/S1070428019010123

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  • DOI: https://doi.org/10.1134/S1070428019010123

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