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Trifluoroacetylation of N-Substituted 1H-1,2-Diazaphenalenes of the Naphthalene and Acenaphthene Series

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Abstract

The acylation of N-substituted 3-methyl-1H-1,2-diazaphenalenes of the naphthalene and acenaphthene series with trifluoroacetic anhydride gave mono- and diacylated products. Despite the presence of a bulky substituent on the pyrrole type nitrogen atom, the trifluoroacetyl group entered the peri position with respect to that substituent. The product structure was confirmed by X-ray analysis.

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Authors and Affiliations

  1. Research Institute of Physical and Organic Chemistry, Southern Federal University, pr. Stachki 194/2, Rostov-on-Don, 344090, Russia

    N. I. Omelichkin, L. G. Minyaeva, M. S. Korobov, G. S. Borodkin & V. V. Mezheritskii

  2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    L. G. Kuz’mina

Authors
  1. N. I. Omelichkin
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  2. L. G. Minyaeva
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  3. M. S. Korobov
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  4. G. S. Borodkin
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  5. L. G. Kuz’mina
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  6. V. V. Mezheritskii
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Correspondence to N. I. Omelichkin.

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Deceased.

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Omelichkin, N.I., Minyaeva, L.G., Korobov, M.S. et al. Trifluoroacetylation of N-Substituted 1H-1,2-Diazaphenalenes of the Naphthalene and Acenaphthene Series. Russ J Org Chem 55, 87–92 (2019). https://doi.org/10.1134/S107042801901010X

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  • DOI: https://doi.org/10.1134/S107042801901010X

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