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Synthesis of 1-, 2-Methoxy-, 1,3-Dimethoxyadamantanes And 1-, 4-Methoxydiadamantanes by Reaction of Adamantyl and Diadamantyl Halides with Dimethyl Carbonate in the Presence of Zeolite Catalysts

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Abstract

1-, 2-Methoxy-, 1,3-dimethoxyadamantane, and 1-, 4-methoxydiadamantane were prepared by the reaction of adamantyl and diadamantyl halides with dimethyl carbonate in the presence of zeolite catalysts NiHY or FeHY free of binders. Optimum ratio of catalysts and reagents were found and the reaction conditions for the selective synthesis of methoxyadamantanoids were developed.

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Authors and Affiliations

  1. Institute of Petrochemistry and Catalysis of the Russian Academy of Scientists, pr. Oktyabrya 141, Ufa, Bashkortostan, 450075, Russia

    R. I. Khusnutdinov, N. A. Shchadneva & Yu. Yu. Mayakova

Authors
  1. R. I. Khusnutdinov
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  2. N. A. Shchadneva
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  3. Yu. Yu. Mayakova
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Corresponding author

Correspondence to Yu. Yu. Mayakova.

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Original Russian Text © R.I. Khusnutdinov, N.A. Shchadneva, Yu.Yu. Mayakova, 2018, published in Zhurnal Organicheskoi Khimii, 2018, Vol. 54, No. 11, pp. 1710–1712.

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Khusnutdinov, R.I., Shchadneva, N.A. & Mayakova, Y.Y. Synthesis of 1-, 2-Methoxy-, 1,3-Dimethoxyadamantanes And 1-, 4-Methoxydiadamantanes by Reaction of Adamantyl and Diadamantyl Halides with Dimethyl Carbonate in the Presence of Zeolite Catalysts. Russ J Org Chem 54, 1728–1730 (2018). https://doi.org/10.1134/S1070428018110180

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  • DOI: https://doi.org/10.1134/S1070428018110180

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