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Unexpected Regioselective Reactions of 2-(Bromomethyl)-1,3-thiaselenole with 1-Methyl-1H-imidazol-2-thiol, Accompanied by Rearrangements

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Abstract

The previously unknown regioselective reactions of 2-(bromomethyl)-1,3-thiaselenole with 1-methyl-1H-imidazol-2-thiol were used to develop efficient synthetic approaches to novel heterocyclic systems, involving C–S and C–N bond formation. The reactions are accompanied by the rearrangements of the starting heterocycles, giving rise to diverse potentially biologically active heterocyclic systems.

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Authors and Affiliations

  1. Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, Irkutsk, 664033, Russia

    S. V. Amosova, A. S. Filippov, V. A. Potapov, N. A. Makhaeva & A. I. Albanov

Authors
  1. S. V. Amosova
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  2. A. S. Filippov
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  3. V. A. Potapov
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  4. N. A. Makhaeva
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  5. A. I. Albanov
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Corresponding author

Correspondence to S. V. Amosova.

Additional information

Original Russian Text © S.V. Amosova, A.S. Filippov, V.A. Potapov, N.A. Makhaeva, A.I. Albanov, 2018, published in Zhurnal Organicheskoi Khimii, 2018, Vol. 54, No. 11, pp. 1682–1686.

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Amosova, S.V., Filippov, A.S., Potapov, V.A. et al. Unexpected Regioselective Reactions of 2-(Bromomethyl)-1,3-thiaselenole with 1-Methyl-1H-imidazol-2-thiol, Accompanied by Rearrangements. Russ J Org Chem 54, 1697–1701 (2018). https://doi.org/10.1134/S107042801811012X

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  • DOI: https://doi.org/10.1134/S107042801811012X

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