Russian Journal of Organic Chemistry

, Volume 53, Issue 5, pp 764–768 | Cite as

Reaction of 1,5-diphenyl-3-arylverdazyles with СН-acids

  • B. S. Tanaseichuk
  • O. B. Tomilin
  • M. K. Pryanichnikova
  • Yu. V. Tsebulaeva
  • O. V. Boyarkina


The presence of electron-donor substituents in the phenyl ring at the atom С3 of the tetrazinyl ring increases, and of electron-acceptor substituents reduces the reaction rate of 1,5-diphenyl-3-arylverdazyl radicals with СН-acids. The reaction is described with a kinetic equation of the second order with respect to verdazyl, the process rate is determined by the energy of the electron transfer from the SOMO (singly occupied molecular orbital) of the radical to the LUMO of the СН-acid.


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Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • B. S. Tanaseichuk
    • 1
  • O. B. Tomilin
    • 1
  • M. K. Pryanichnikova
    • 1
  • Yu. V. Tsebulaeva
    • 1
  • O. V. Boyarkina
    • 1
  1. 1.Mordovian State UniversitySaranskRussia

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