Russian Journal of Organic Chemistry

, Volume 53, Issue 5, pp 720–728 | Cite as

Methods of synthesis of alicyclic 1,5,9-triketones. Reaction of transaminomethylation

  • T. I. Akimova
  • O. A. Soldatkina
  • Zh. A. Ivanenko
  • V. G. Savchenko
Article
  • 36 Downloads

Abstract

Alicyclic 1,5,9-triketones with various combination of 5-, 6-, 7-membereded cycles in the molecule were obtained by methods of diketone condensation, Michael reaction, and proceeding from Mannich mono- and bisbases and cycloalkanones. The latter method was accompanied with a transaminomethylation, observed for the first time at triketones preparation. The structures of cyclic forms of Michael reaction products were refined.

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Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • T. I. Akimova
    • 1
  • O. A. Soldatkina
    • 1
  • Zh. A. Ivanenko
    • 1
  • V. G. Savchenko
    • 1
  1. 1.Far-Eastern Federal UniversityVladivostokRussia

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