Russian Journal of Organic Chemistry

, Volume 53, Issue 5, pp 697–708 | Cite as

Atropisomeric N-acyl-N-(cyclopentenylphenyl)glycines in the synthesis of oxazolo[3,4-a]benzoxazocinones

  • R. R. Gataullin
  • Z. A. Ibatullina
  • E. S. Meshcheryakova
  • A. A. Fatykhov
  • L. M. Khalilov
Article
  • 61 Downloads

Abstract

Intramolecular [3+2]-cycloaddition was studied of munchnones generated at heating syn- and anti-atropisomers of N-acyl-N-[6-methyl-2-(cyclopent-2-en-1-yl)phenyl]glycines with acetic anhydride. By spectral and X-ray diffraction analysis syn-isomers of acids and tetrahydro-1,4,7-methanetriyl[1,3]oxazolo[3,4-a][1]- bensazocin-3(3aH)-ones were identified.

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Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • R. R. Gataullin
    • 1
  • Z. A. Ibatullina
    • 2
  • E. S. Meshcheryakova
    • 3
  • A. A. Fatykhov
    • 1
  • L. M. Khalilov
    • 3
  1. 1.Ufa Institute of ChemistryRussian Academy of SciencesUfaRussia
  2. 2.Ufa Institute of BiologyRussian Academy of SciencesUfaRussia
  3. 3.Institute of Petrochemistry and CatalysisRussian Academy of SciencesUfaRussia

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