Russian Journal of Organic Chemistry

, Volume 53, Issue 5, pp 679–685 | Cite as

Relative stability of 1-(4-R-2,6-dinitrophenyl)-2,2-diphenylhydrazides

  • B. S. Tanaseichuk
  • O. B. Tomilin
  • M. K. Pryanichnikova
  • O. V. Boyarkina
  • A. A. Burtasov
Article
  • 33 Downloads

Abstract

Substitution of the nitro group for methyl in the position 4 of the picrylic fragment of 1-(2,4,6-trinitrophenyl)-2,2-diphenylhydrazyl increases the relative stability of hydrazyl radical in reaction with CH-acids. The reaction rate of 1-(2,4,6-trinitrophenyl)-2,2-diphenylhydrazyl with acetylacetone and ethyl acetoacetate is described with equations of first order with respect to the radical and the СН-acid and is determined by the energy of electron transfer from HOMO of СН-acid on LUMO of the radical, which is its acceptor.

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Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • B. S. Tanaseichuk
    • 1
  • O. B. Tomilin
    • 1
  • M. K. Pryanichnikova
    • 1
  • O. V. Boyarkina
    • 1
  • A. A. Burtasov
    • 1
  1. 1.Mordovian State UniversitySaranskRussia

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