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Russian Journal of Organic Chemistry

, Volume 53, Issue 5, pp 652–655 | Cite as

Regioselective synthesis of functional tellanes from tellurium tetrahalides and 1-octene

  • S. I. Udalova
  • M. V. Musalova
  • M. V. Musalov
  • V. A. Potapov
  • S. V. Amosova
Article

Abstract

Proceeding from TeCl4 and 1-octene a regioselective method was developed of the synthesis of trichloro(2-chlorooctyl)tellane. At adding methanol to this compound chlorine was easily replaced at room temperature by a methoxy group affording trichloro(2-methoxyoctyl)tellane. The reaction of TeBr4 with 1-octene in methanol resulted in tribromo(2-methoxyoctyl)tellane. A reduction of trichloro- and tribromo(2-methoxyoctyl)tellanes occurs the most selectively in the system NaBH4–water–THF giving 1,2-bis(2-methoxyoctyl)ditellane. The reactions are characterized by a high selectivity and quantitative yields of the products.

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Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • S. I. Udalova
    • 1
  • M. V. Musalova
    • 1
  • M. V. Musalov
    • 1
  • V. A. Potapov
    • 1
  • S. V. Amosova
    • 1
  1. 1.Favorskii Irkutsk Institute of Chemistry, Siberian BranchRussian Academy of SciencesIrkutskRussia

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