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Russian Journal of Organic Chemistry

, Volume 51, Issue 10, pp 1359–1367 | Cite as

Reaction of monoterpene hydroxy thiols with chlorine dioxide

  • O. M. Lezina
  • O. N. Grebenkina
  • D. V. Sudarikov
  • Yu. V. Krymskaya
  • S. A. Rubtsova
  • A. V. Kutchin
Article

Abstract

Reactions of isobornane and pinane hydroxy thiols with chlorine dioxide have been studied. Unlike pinane derivatives, hydroxy thiols of the isobornane series reacted with chlorine dioxide to give the corresponding sulfinyl derivatives with high stereoselectivity. New terpenoids containing sulfur, oxygen, and chlorine atoms have been synthesized by oxidation of hydroxy thiols with chlorine dioxide.

Keywords

Sulfonic Acid Chlorine Dioxide Sulfonyl Chloride Sultone Sulfinyl 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Pleiades Publishing, Ltd. 2015

Authors and Affiliations

  • O. M. Lezina
    • 1
  • O. N. Grebenkina
    • 1
  • D. V. Sudarikov
    • 1
  • Yu. V. Krymskaya
    • 1
  • S. A. Rubtsova
    • 1
  • A. V. Kutchin
    • 1
  1. 1.Institute of Chemistry, Komi Research CenterUral Branch, Russian Academy of SciencesSyktyvkarRussia

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