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Russian Journal of Organic Chemistry

, Volume 51, Issue 3, pp 309–312 | Cite as

Synthesis and properties of new thiophosphorylated thioureas containing a trialkoxysilyl group

  • L. I. Vagapova
  • D. R. Sharafutdinova
  • A. R. Burilov
  • A. R. Mustafina
  • V. M. Babaev
  • I. Kh. Rizvanov
  • M. A. Pudovik
Article

Abstract

Reactions of thiophosphoryl isothiocyanates with 3-(triethoxysilyl)propan-1-amine afforded new thiophosphorylated thioureas containing a triethoxysilyl group. The formation of 2: 1 complexes of 1-(di-butoxythiophosphoryl)-3-(3-triethoxysilylpropyl)thiourea with Co(II), Ni(II), and Zn(II) acetates was detected by MALDI mass spectrometry. The copper(II) complex underwent reduction to copper(I) during the recording of the MALDI mass spectrum, and signals from cluster ions [3M − 3H + 4Cu]+ were observed.

Keywords

Thiourea MALDI Mass Spectrum MALDI Mass Spectrometry Triethoxysilyl Oily Material 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Pleiades Publishing, Ltd. 2015

Authors and Affiliations

  • L. I. Vagapova
    • 1
  • D. R. Sharafutdinova
    • 1
  • A. R. Burilov
    • 1
  • A. R. Mustafina
    • 1
  • V. M. Babaev
    • 1
  • I. Kh. Rizvanov
    • 1
  • M. A. Pudovik
    • 1
  1. 1.Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific CenterRussian Academy of SciencesKazanTatarstan, Russia

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