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Russian Journal of Organic Chemistry

, Volume 50, Issue 6, pp 805–809 | Cite as

Synthesis of acylhydrazones of sterically hindered hydroxybenzaldehydes based on phloroglucinol

  • T. A. Barsukova
  • G. N. Nugumanova
  • S. V. Bukharov
  • S. N. Podyachev
  • V. V. Syakaev
  • N. A. Mukmeneva
  • R. Ya. Deberdeev
Article
  • 84 Downloads

Abstract

New acylhydrazones containing sterically hindered phenolic fragments with different degrees of steric shielding were synthesized by reactions of 2,2′,2″-[benzene-1,3,5-triyltris(oxy)]triacetic acid trishydrazide with hydroxybenzaldehydes. According to the NMR data, the products in solution exist as relatively stable conformational cis/trans isomers with respect to the C(O)-NH bond.

Keywords

Hydrazide Hydrazone Hydrazine Hydrate Phloroglucinol Hydroxybenzaldehydes 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Pleiades Publishing, Ltd. 2014

Authors and Affiliations

  • T. A. Barsukova
    • 1
  • G. N. Nugumanova
    • 2
  • S. V. Bukharov
    • 2
  • S. N. Podyachev
    • 1
  • V. V. Syakaev
    • 1
  • N. A. Mukmeneva
    • 2
  • R. Ya. Deberdeev
    • 2
  1. 1.Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific CenterRussian Academy of SciencesKazanTatarstan, Russia
  2. 2.Kazan National Research Technological UniversityKazanTatarstan, Russia

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