Abstract
New derivatives of the (+)-enantiomer of o-bornylphenol were synthesized with a view to determine the configuration of chiral centers therein. The absolute configuration of the terpene substituents in the Mannich reaction product obtained from 4,13-diaza-18-crown-6 was estimated as (1R,2R,4S) on the basis of anomalous X-ray scattering.
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Original Russian Text © E.V. Buravlev, I.Yu. Chukicheva, O.A. Shumova, K.Yu. Suponitskii, A.V. Kutchin, 2013, published in Zhurnal Organicheskoi Khimii, 2013, Vol. 49, No. 9, pp. 1317–1322.
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Buravlev, E.V., Chukicheva, I.Y., Shumova, O.A. et al. o-Bornylphenol: Stereochemistry and synthesis of new derivatives from its (+)-enantiomer. Russ J Org Chem 49, 1300–1306 (2013). https://doi.org/10.1134/S1070428013090108
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DOI: https://doi.org/10.1134/S1070428013090108