Russian Journal of Organic Chemistry

, Volume 49, Issue 9, pp 1300–1306 | Cite as

o-Bornylphenol: Stereochemistry and synthesis of new derivatives from its (+)-enantiomer

  • E. V. Buravlev
  • I. Yu. Chukicheva
  • O. A. Shumova
  • K. Yu. Suponitskii
  • A. V. Kutchin
Article

Abstract

New derivatives of the (+)-enantiomer of o-bornylphenol were synthesized with a view to determine the configuration of chiral centers therein. The absolute configuration of the terpene substituents in the Mannich reaction product obtained from 4,13-diaza-18-crown-6 was estimated as (1R,2R,4S) on the basis of anomalous X-ray scattering.

Keywords

Chiral Center Bromocresol Purple Isobornyl Final Divergence Factor Light Yellow Oily Substance 

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Copyright information

© Pleiades Publishing, Ltd. 2013

Authors and Affiliations

  • E. V. Buravlev
    • 1
  • I. Yu. Chukicheva
    • 1
  • O. A. Shumova
    • 1
  • K. Yu. Suponitskii
    • 2
  • A. V. Kutchin
    • 1
  1. 1.Institute of Chemistry, Komi Research Center, Ural BranchRussian Academy of SciencesSyktyvkarRussia
  2. 2.Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussia

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