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Russian Journal of Organic Chemistry

, Volume 49, Issue 5, pp 669–671 | Cite as

Fe-catalyzed synthesis of (4E)-tridec-4-en-1-yl acetate, sex pheromone of tomato pinworm (Keiferia lycopersicella)

  • R. N. Shakhmaev
  • A. Sh. Sunagatullina
  • V. V. Zorin
Article

Abstract

Starting with industrially available 1,3-dichloropropene a stereoselective process was developed for the preparation of (4E)-tridec-4-en-1-yl acetate, sex pheromone of tomato pinworm (Keiferia lycopersicella) using in the key stage the Fe-catalyzed cross-coupling of ethyl (4E)-5-chloropent-4-enoate with octylmagnesium bromide.

Keywords

Oily Substance Aluminum Hydride Lithium Aluminum Hydride Anhydrous Ether Claisen Rearrangement 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Pleiades Publishing, Ltd. 2013

Authors and Affiliations

  • R. N. Shakhmaev
    • 1
  • A. Sh. Sunagatullina
    • 1
  • V. V. Zorin
    • 1
  1. 1.Ufa State Oil Engineering UniversityUfaRussia

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