Russian Journal of Organic Chemistry

, Volume 49, Issue 1, pp 67–69 | Cite as

Arylation of geminally activated nitroethenes

  • R. I. Baichurin
  • N. I. Aboskalova
  • E. V. Trukhin
  • V. M. Berestovitskaya


3-Aryl-2-nitroprop-2-enenitriles and 1,3-diphenyl-2-nitroprop-2-en-1-one reacted with N,N-dimethylaniline to give the corresponding arylation products, 3-aryl-3-(4-dimethylaminophenyl)-2-nitropropanenitriles and 3-(4-dimethylaminophenyl)-1,3-diphenyl-2-nitropropan-1-one, whose structure was confirmed by IR and 1H and 13C-{1H} spectroscopy with the use of 1H-13C HMQC and HMBC heteronuclear correlation techniques.


Brilliant Green Nitroethenes Methylaniline Nitrostyrene Diphenylurea 
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Copyright information

© Pleiades Publishing, Ltd. 2013

Authors and Affiliations

  • R. I. Baichurin
    • 1
  • N. I. Aboskalova
    • 1
  • E. V. Trukhin
    • 1
  • V. M. Berestovitskaya
    • 1
  1. 1.Herzen State Pedagogical University of RussiaSt. PetersburgRussia

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