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Russian Journal of Organic Chemistry

, Volume 48, Issue 1, pp 99–103 | Cite as

Catalytic cycloaddition of diazoalkanes with heterocyclic substituents to fullerene C60

  • A. R. Tuktarov
  • A. A. Khuzin
  • V. V. Korolev
  • U. M. Dzhemilev
Article

Abstract

Methanofullerenes were directly synthesized under mild conditions by cycloaddition to fullerene C60 of diazoalkanes generated in situ by oxidation of ketone hydrazones containing a heterocyclic fragment with manganese(IV) oxide in the presence of the catalytic system Pd(acac)2-2 PPh3-4 Et3Al.

Keywords

Fullerene Acac Diazo Compound Diazoacetates Heterocyclic Fragment 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Pleiades Publishing, Ltd. 2012

Authors and Affiliations

  • A. R. Tuktarov
    • 1
  • A. A. Khuzin
    • 1
  • V. V. Korolev
    • 1
  • U. M. Dzhemilev
    • 1
  1. 1.Institute of Petrochemistry and CatalysisRussian Academy of SciencesUfaBashkortostan, Russia

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