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Palladium complex of 6-(2-hydroxy-5-methylphenyl)-3-(pyridin-2-yl)-1,2,4-triazin-5(2H)-one: Synthesis, structure, and catalytic activity

  • A. V. Mekhaev
  • A. V. Pestov
  • P. A. Slepukhin
  • Yu. G. Yatluk
  • M. G. Pervova
  • M. A. Samorukova
  • O. N. Chupakhin
Article

Abstract

Palladium(II) complex with 6-(2-hydroxy-5-methylphenyl)-3-(pyridin-2-yl)-1,2,4-triazin-5(2H)-one was synthesized for the first time. The ligand was prepared from 3-(pyridin-2-yl)-1,2,4-triazin-5(2H)-one and 4-methylphenol via nucleophilic substitution of hydrogen (S N H reaction). The complex was readily soluble in basic medium, and it effectively catalyzed Mizoroki-Heck reaction.

Keywords

Butyl Acrylate Palladium Complex Heck Reaction Iodobenzene Triazine Ring 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Pleiades Publishing, Ltd. 2011

Authors and Affiliations

  • A. V. Mekhaev
    • 1
  • A. V. Pestov
    • 1
  • P. A. Slepukhin
    • 1
  • Yu. G. Yatluk
    • 1
  • M. G. Pervova
    • 1
  • M. A. Samorukova
    • 1
  • O. N. Chupakhin
    • 1
  1. 1.Postovskii Institute of Organic Synthesis, Ural DivisionRussian Academy of SciencesYekaterinburgRussia

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