Chemistry of naphthazarin derivatives: XV. Bromination of naphthazarin and its derivatives

  • N. D. Pokhilo
  • A. Ya. Yakubovskaya
  • V. P. Glazunov
Article
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Abstract

Bromination of a number of naphthazarin (5,8-dihydroxy-1,4-naphthoquinone) derivatives having different substituents in the aromatic ring with molecular bromine in carbon tetrachloride was studied. Preparative procedures for the synthesis of 2-bromo-5,8-dihydroxy-7-methoxy-1,4-naphthoquinone, 2-bromo-6,7-dichloro-5,8-dihydroxy-1,4-naphthoquinone, 2-bromo-3,5,8-trihydroxy-1,4-naphthoquinone, and 2-bromo-6,7-dichloro-3,5,8-trihydroxy-1,4-naphthoquinone were developed.

Keywords

Carbon Tetrachloride Naphthoquinone Juglone Quinoid Ring Naphthazarin 

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Copyright information

© Pleiades Publishing, Ltd. 2011

Authors and Affiliations

  • N. D. Pokhilo
    • 1
  • A. Ya. Yakubovskaya
    • 1
  • V. P. Glazunov
    • 1
  1. 1.Pacific Institute of Bioorganic Chemistry, Far East DivisionRussian Academy of SciencesVladivostokRussia

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