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Russian Journal of Organic Chemistry

, Volume 46, Issue 10, pp 1476–1478 | Cite as

Acyl Iodides in Organic Synthesis. Reaction of Acyl Iodides with N,N-Dimethyl Carboxylic Acid Amides

  • M. G. Voronkov
  • I. P. Tsyrendorzhieva
  • V. I. Rakhlin
Review

Abstract

Acyl iodides RCOI (R = Me, Ph) reacted with N,N-dimethylformamide and N,N-dimethylacetamide Me2NC(=O)R’ (R’ = H, Me) along two concurrent pathways involving transacylation and cleavage of the Me-N bond. The first pathway leads to the formation of acyl group exchange products, and the second, to the corresponding imides R’CON(Me)COR.

Keywords

Iodide Imide Vacuum Distillation Methyl Iodide Sodium Iodide 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Pleiades Publishing, Ltd. 2010

Authors and Affiliations

  • M. G. Voronkov
    • 1
  • I. P. Tsyrendorzhieva
    • 1
  • V. I. Rakhlin
    • 1
  1. 1.Favorskii Irkutsk Institute of Chemistry, Siberian DivisionRussian Academy of SciencesIrkutskRussia

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