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Five-membered 2,3-dioxoheterocycles: LXVII. Pyrroledione-pyrroledion recyclization of isopropyl 2-(1-aryl-4,5-dioxo-2-phenyl-4,5-dihydro-1H-pyrrol-3-yl)-2-oxoacetates under the action of arylamines. Crystal and molecular structure of (z)-isopropyl 2-hydroxy-4,5-dioxo-1-phenyl-3-[phenyl(phenylamino)-methylene]pyrrolidine-2-carboxylate

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Abstract

Reactions of isopropyl 2-(1-aryl-4,5-dioxo-2-phenyl-4,5-dihydro-1H-pyrrol-3-yl)-2-oxoacetates with aromatic amines involve a pyrroledione-pyrroledione recyclization to form isopropyl 1-aryl-2-hydroxy-4,5-dioxo-3-[phenyl(arylamino)methylene]pyrrolidine-2-carboxylates. The crystal and molecular structure of (Z)-isopropyl 2-hydroxy-4,5-dioxo-1-phenyl-3-[phenyl(phenylamino)methylene]pyrrolidine-2-carboxylate was proved by XRD analysis.

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Authors and Affiliations

  1. Perm State University, Perm, 614990, Russia

    P. S. Silaichev, M. V. Dmitriev & A. N. Maslivets

  2. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Russia

    Z. G. Aliev

Authors
  1. P. S. Silaichev
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  2. M. V. Dmitriev
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  3. Z. G. Aliev
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  4. A. N. Maslivets
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Correspondence to P. S. Silaichev.

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Original Russian Text © P.S. Silaichev, M.V. Dmitriev, Z.G. Aliev, A.N. Maslivets, 2009, published in Zhurnal Organicheskoi Khimii, 2010, Vol. 46, No. 2, pp. 261–264.

For Communication LXVI, see [1].

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Silaichev, P.S., Dmitriev, M.V., Aliev, Z.G. et al. Five-membered 2,3-dioxoheterocycles: LXVII. Pyrroledione-pyrroledion recyclization of isopropyl 2-(1-aryl-4,5-dioxo-2-phenyl-4,5-dihydro-1H-pyrrol-3-yl)-2-oxoacetates under the action of arylamines. Crystal and molecular structure of (z)-isopropyl 2-hydroxy-4,5-dioxo-1-phenyl-3-[phenyl(phenylamino)-methylene]pyrrolidine-2-carboxylate. Russ J Org Chem 46, 255–259 (2010). https://doi.org/10.1134/S1070428010020193

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  • DOI: https://doi.org/10.1134/S1070428010020193

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