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Palladium nanoparticles stabilized by a copolymer of N-vinylimidazole with N-vinylcaprolactam as efficient recyclable catalyst of aromatic cyanation

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Abstract

A new recyclable catalytic system was developed based on palladium nanoparticles and a copolymer of N-vinylimidazole and N-vinylcaprolactam for cyanation of aromatic bromides. The source of the cyanide ion was a nontoxic potassium hexacyanoferrate.

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Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, 119991, Russia

    A. V. Selivanova, V. S. Tyurin & V. V. Matveev

  2. Lomonosov Moscow State University, Moscow, Russia

    I. P. Beletskaya & A. R. Khokhlov

Authors
  1. I. P. Beletskaya
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  2. A. V. Selivanova
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  3. V. S. Tyurin
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  4. V. V. Matveev
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  5. A. R. Khokhlov
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Correspondence to I. P. Beletskaya.

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Original Russian Text © I.P. Beletskaya, A.V. Selivanov, V.S. Tyurin, V.V. Matveev, A.R. Khokhlov, 2009, published in Zhurnal Organicheskoi Khimii, 2010, Vol. 46, No. 2, pp. 167–171.

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Beletskaya, I.P., Selivanova, A.V., Tyurin, V.S. et al. Palladium nanoparticles stabilized by a copolymer of N-vinylimidazole with N-vinylcaprolactam as efficient recyclable catalyst of aromatic cyanation. Russ J Org Chem 46, 157–161 (2010). https://doi.org/10.1134/S1070428010020016

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  • DOI: https://doi.org/10.1134/S1070428010020016

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