Russian Journal of Organic Chemistry

, Volume 45, Issue 8, pp 1164–1167 | Cite as

Reactions of substituted 8-oxatricyclo[3.2.1.02,4]octan-6-ones and 9-oxatricyclo[3.3.1.02,4]nonan-6-ones with methylmagnesium bromide and lithium aluminum hydride

  • A. P. Molchanov
  • V. V. Diev
  • Chan Quang Tung
  • R. R. Kostikov
Article

Abstract

Substituted 8-oxatricyclo[3.2.1.02,4]octan-6-one and 9-oxatricyclo[3.3.1.02,4]-nonan-6-one obtained by treating substituted cyclopropenes with carbonyl ylides in reactions with methylmagnesium bromide and lithium aluminum hydride were stereoselectively converted into the corresponding alcohols.

Keywords

Cyclopropane Lithium Aluminum Hydride Diazo Compound Magnesium Bromide Eluent Hexane 

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Copyright information

© Pleiades Publishing, Ltd. 2009

Authors and Affiliations

  • A. P. Molchanov
    • 1
  • V. V. Diev
    • 1
  • Chan Quang Tung
    • 1
  • R. R. Kostikov
    • 1
  1. 1.St. Petersburg State UniversitySt. PetersburgRussia

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