Advertisement

Russian Journal of Organic Chemistry

, Volume 43, Issue 12, pp 1821–1824 | Cite as

One-step synthesis of 3-dichloromethylpyridine from pyridine in the presence of iron-containing catalysts

  • R. I. Khusnutdinov
  • A. R. Baiguzina
  • A. A. Smirnov
  • R. R. Mukminov
  • U. M. Dzhemilev
Article

Abstract

3-Dichloromethylpyridine was synthesized by reaction of pyridine with the system MeOH-CCl4-iron catalyst [FeBr2, Fe3(CO)12, or iron(III) naphthenate]. Iron(II) bromide at a FeBr2-pyridine-CCl4-MeOH ratio of 1:100:200:200 showed the highest catalytic activity.

Keywords

MeOH Carbon Tetrachloride Hydrogen Chloride Pyridine Hydrochloride Molar Ratio Catalyst 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    Kovganko, N.V. and Kashkan, Zh.N., Russ. J. Org. Chem., 2004, vol. 40, p. 1709.CrossRefGoogle Scholar
  2. 2.
    Nishiyama, R., Fujikawa, K., Haga, T., and Hase, K., JPN Patent Appl. no. 55-022 617, 1980.Google Scholar
  3. 3.
    Jelich, K., US Patent no. 5 116 993, 1992.Google Scholar
  4. 4.
    Jelich, K., JPN Patent Appl. no. 11-140 053, 1999.Google Scholar
  5. 5.
    Bowden, R. and Seaton, T., UK Patent no. 1 599 783, 1982; Ref. Zh., Khim., 1982, no. 15N163P.Google Scholar
  6. 6.
    Rubina, K.I., Iovel’, I.G., Gol’dberg, Yu.Sh., and Shimanskaya, M.V., Khim. Geterotsikl. Soedin., 1989, p. 543.Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2007

Authors and Affiliations

  • R. I. Khusnutdinov
    • 1
  • A. R. Baiguzina
    • 1
  • A. A. Smirnov
    • 1
  • R. R. Mukminov
    • 1
  • U. M. Dzhemilev
    • 1
  1. 1.Institute of Petroleum Chemistry and CatalysisRussian Academy of SciencesUfaRussia

Personalised recommendations