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One-step synthesis of 3-dichloromethylpyridine from pyridine in the presence of iron-containing catalysts

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Abstract

3-Dichloromethylpyridine was synthesized by reaction of pyridine with the system MeOH-CCl4-iron catalyst [FeBr2, Fe3(CO)12, or iron(III) naphthenate]. Iron(II) bromide at a FeBr2-pyridine-CCl4-MeOH ratio of 1:100:200:200 showed the highest catalytic activity.

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References

  1. Kovganko, N.V. and Kashkan, Zh.N., Russ. J. Org. Chem., 2004, vol. 40, p. 1709.

    Article  CAS  Google Scholar 

  2. Nishiyama, R., Fujikawa, K., Haga, T., and Hase, K., JPN Patent Appl. no. 55-022 617, 1980.

  3. Jelich, K., US Patent no. 5 116 993, 1992.

  4. Jelich, K., JPN Patent Appl. no. 11-140 053, 1999.

  5. Bowden, R. and Seaton, T., UK Patent no. 1 599 783, 1982; Ref. Zh., Khim., 1982, no. 15N163P.

  6. Rubina, K.I., Iovel’, I.G., Gol’dberg, Yu.Sh., and Shimanskaya, M.V., Khim. Geterotsikl. Soedin., 1989, p. 543.

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Authors and Affiliations

  1. Institute of Petroleum Chemistry and Catalysis, Russian Academy of Sciences, pr. Oktyabrya 141, Ufa, 450075, Bashkortostan, Russia

    R. I. Khusnutdinov, A. R. Baiguzina, A. A. Smirnov, R. R. Mukminov & U. M. Dzhemilev

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  1. R. I. Khusnutdinov
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  2. A. R. Baiguzina
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  3. A. A. Smirnov
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  4. R. R. Mukminov
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  5. U. M. Dzhemilev
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Correspondence to R. I. Khusnutdinov.

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Original Russian Text © R.I. Khusnutdinov, A.R. Baiguzina, A.A. Smirnov, R.R. Mukminov, U.M. Dzhemilev, 2007, published in Zhurnal Organicheskoi Khimii, 2007, Vol. 43, No. 12, pp. 1819–1821.

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Khusnutdinov, R.I., Baiguzina, A.R., Smirnov, A.A. et al. One-step synthesis of 3-dichloromethylpyridine from pyridine in the presence of iron-containing catalysts. Russ J Org Chem 43, 1821–1824 (2007). https://doi.org/10.1134/S1070428007120147

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  • DOI: https://doi.org/10.1134/S1070428007120147

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