Russian Journal of Organic Chemistry

, Volume 43, Issue 9, pp 1393–1396 | Cite as

Efficient procedure for chemoselective N-nitrosation of secondary amines with trichloromelamine-NaNO2

  • A. Bamoniri
  • M. A. Zolfigol
  • B. F. Mirjalili
  • F. Fallah
Article

Abstract

A combination of trichloromelamine and sodium nitrite in the presence of wet silica gel was used as an effective nitrosating agent for the transformation of secondary amines into the corresponding N-nitroso derivatives under mild and heterogeneous conditions in good to excellent yields.

Keywords

Melamine Secondary Amine Sodium Nitrite Phenylamino Diaza Crown 

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Copyright information

© Pleiades Publishing, Ltd. 2007

Authors and Affiliations

  • A. Bamoniri
    • 1
  • M. A. Zolfigol
    • 2
  • B. F. Mirjalili
    • 3
  • F. Fallah
    • 1
  1. 1.Department of Chemistry, College of ScienceKashan UniversityKashanIran
  2. 2.Chemistry Department, College of ScienceBu-Ali Sina UniversityHamadanIran
  3. 3.Department of Chemistry, College of ScienceYazd UniversityYazdIran

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