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Hydrogenation of α-oxophosphonates with molecular hydrogen catalyzed by palladium on carbon carrier as synthesis procedure for α-hydroxyphosphonates

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Abstract

Hydrogenation with molecular hydrogen of substituted benzoylphosphonic acids ethyl esters provides a convenient preparation method for diethyl [hydroxy(aryl)methyl]phosphonates. Both the palladium on activated carbon and the palladium immobilized in a chitosan matrix applied on a carbon carrier sibunit can be employed as catalysts.

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Authors and Affiliations

  1. Moscow State University, Moscow, 119992, Russia

    N. S. Gulyukina, G. N. Bondarenko, A. D. Averin & I. P. Beletskaya

  2. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russia

    V. I. Isaeva, E. D. Finashina & L. M. Kustov

Authors
  1. N. S. Gulyukina
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  2. G. N. Bondarenko
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  3. A. D. Averin
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  4. V. I. Isaeva
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  5. E. D. Finashina
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  6. L. M. Kustov
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  7. I. P. Beletskaya
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Corresponding author

Correspondence to N. S. Gulyukina.

Additional information

Original Russian Text © N.S. Gulyukina, G.N. Bondarenko, A.D. Averin, V.I. Isaeva, E.D. Finashina, L.M. Kustov, I.P. Beletskaya, 2007, published in Zhurnal Organicheskoi Khimii, 2007, Vol. 43, No. 8, pp. 1186–1191.

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Gulyukina, N.S., Bondarenko, G.N., Averin, A.D. et al. Hydrogenation of α-oxophosphonates with molecular hydrogen catalyzed by palladium on carbon carrier as synthesis procedure for α-hydroxyphosphonates. Russ J Org Chem 43, 1180–1185 (2007). https://doi.org/10.1134/S1070428007080167

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  • DOI: https://doi.org/10.1134/S1070428007080167

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