Russian Journal of Organic Chemistry

, Volume 43, Issue 6, pp 911–914 | Cite as

Cyclopropanecarbaldehyde with two protected hydroxymethyl groups

  • B. A. Baimashev
  • V. Yu. Fedorenko
  • A. M. Polozov
  • Yu. G. Shtyrlin
  • E. N. Klimovitskii


3,5-Dioxabicyclo[5.1.0]octane-8-carbaldehyde was synthesized in three steps, including initial stereoselective exo-cyclopropanation of 1,3-dioxacyclohept-5-ene with ethyl diazoacetate. The subsequent phosphorylation according to Abramov and Kabachnik-Fields gave the corresponding α-hydroxy(acetoxy)- and α-aminocyclopropylmethylphosphonates with protected hydroxymethyl moieties at the three-membered ring.


Oily Substance Methylphosphonate Pyridinium Chlorochromate Ethyl Diazoacetate Light Yellow Oily Substance 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.


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Copyright information

© Pleiades Publishing, Ltd. 2007

Authors and Affiliations

  • B. A. Baimashev
    • 1
  • V. Yu. Fedorenko
    • 1
  • A. M. Polozov
    • 1
  • Yu. G. Shtyrlin
    • 1
  • E. N. Klimovitskii
    • 1
  1. 1.Butlerov Chemical InstituteKazan State UniversityKazanRussia

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