Russian Journal of Organic Chemistry

, Volume 43, Issue 6, pp 911–914 | Cite as

Cyclopropanecarbaldehyde with two protected hydroxymethyl groups

  • B. A. Baimashev
  • V. Yu. Fedorenko
  • A. M. Polozov
  • Yu. G. Shtyrlin
  • E. N. Klimovitskii
Article

Abstract

3,5-Dioxabicyclo[5.1.0]octane-8-carbaldehyde was synthesized in three steps, including initial stereoselective exo-cyclopropanation of 1,3-dioxacyclohept-5-ene with ethyl diazoacetate. The subsequent phosphorylation according to Abramov and Kabachnik-Fields gave the corresponding α-hydroxy(acetoxy)- and α-aminocyclopropylmethylphosphonates with protected hydroxymethyl moieties at the three-membered ring.

Keywords

Oily Substance Methylphosphonate Pyridinium Chlorochromate Ethyl Diazoacetate Light Yellow Oily Substance 

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Copyright information

© Pleiades Publishing, Ltd. 2007

Authors and Affiliations

  • B. A. Baimashev
    • 1
  • V. Yu. Fedorenko
    • 1
  • A. M. Polozov
    • 1
  • Yu. G. Shtyrlin
    • 1
  • E. N. Klimovitskii
    • 1
  1. 1.Butlerov Chemical InstituteKazan State UniversityKazanRussia

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