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Russian Journal of Organic Chemistry

, Volume 43, Issue 3, pp 347–351 | Cite as

Aluminacyclopentanes in the synthesis of ethyl 1-hydroxycyclopentanecarboxylates

  • U. M. Dzhemilev
  • A. G. Ibragimov
  • L. O. Khafizova
  • R. R. Gilyazev
  • A. L. Makhamatkhanova
Article

Abstract

A one-pot procedure has been developed for the synthesis of ethyl 1-hydroxycyclopentanecarboxylates. The procedure includes cycloalumination of terminal olefins with triethylaluminum in the presence of Cp2ZrCl2, reaction of alkyl-substituted aluminacyclopentanes formed in situ with diethyl oxalate in the presence of a catalytic amount of copper salt, and acid hydrolysis.

Keywords

Fullerene Trans Isomer CuBr Terminal Olefin Diethyl Oxalate 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Pleiades Publishing, Ltd. 2007

Authors and Affiliations

  • U. M. Dzhemilev
    • 1
  • A. G. Ibragimov
    • 1
  • L. O. Khafizova
    • 1
  • R. R. Gilyazev
    • 1
  • A. L. Makhamatkhanova
    • 1
  1. 1.Institute of Petroleum Chemistry and CatalysisRussian Academy of SciencesUfaRussia

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