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Russian Journal of Organic Chemistry

, Volume 42, Issue 11, pp 1615–1621 | Cite as

Oxidation of monohydric and dihydric alcohols with CCl4 catalyzed by molybdenum compounds

  • R. I. Khusnutdinov
  • N. A. Shchadneva
  • R. Yu. Burangulova
  • Z. S. Muslimov
  • U. M. Dzhemilev
Article

Abstract

Mo(CO)6 catalyzed oxidation of alcohols and diols with tetrachloromethane. Primary oxidation products in reaction of alcohols with CCl4 are alkyl hypochlorites, and final products depending on the structure of initial alcohol are aldehydes (as acetals), ketones, chloroketones, and esters.

Keywords

Tetrachloromethane Molybdenum Compound Hexachloroethane Butyl Butyrate Acetic Aldehyde 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Pleiades Publishing, Inc. 2006

Authors and Affiliations

  • R. I. Khusnutdinov
    • 1
  • N. A. Shchadneva
    • 1
  • R. Yu. Burangulova
    • 1
  • Z. S. Muslimov
    • 1
  • U. M. Dzhemilev
    • 1
  1. 1.Institute of Petrochemistry and CatalysisRussian Academy of SciencesUfaRussia

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