Russian Journal of Organic Chemistry

, Volume 42, Issue 4, pp 591–595 | Cite as

Reactions of 6,6-dialkyl-5,7-dioxo-4,8-dioxaspiro[2.5]octane-1,1,2,2-tetracarbonitriles with O-centered nucleophiles

  • O. V. Kayukova
  • Ya. S. Kayukov
  • A. N. Nikolaev
  • O. V. Ershov
  • A. V. Eremkin
  • O. E. Nasakin
Article

Abstract

The reactions of 6,6-dialkyl-5,7-dioxo-4,8-dioxaspiro[2.5]octane-1,1,2,2-tetracarbonitriles with primary aliphatic alcohols lead to the formation of alkyl 2,2,3,3-tetracyanocyclopropanecarboxylates; the reactions of the same compounds with ketone oximes give 2-amino-4,4-bis(alkylideneaminooxy)-6-(alkylidene-aminooxycarbonyl)-3-azabicyclo[3.1.0]hex-2-ene-1,5-dicarbonitriles, while with aldehyde oximes 2-amino-2-oxo-1,5-dicyano-3-azabicyclo[3.1.0]hex-2-ene-6-carboxylic acid is formed.

Keywords

Alcohol Organic Chemistry Aldehyde Ketone Oxime 

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Copyright information

© Pleiades Publishing, Inc. 2006

Authors and Affiliations

  • O. V. Kayukova
    • 1
  • Ya. S. Kayukov
    • 1
  • A. N. Nikolaev
    • 1
  • O. V. Ershov
    • 1
  • A. V. Eremkin
    • 1
  • O. E. Nasakin
    • 1
  1. 1.I.N. Ul’yanov Chuvash State UniversityCheboksaryRussia

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