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Synthesis of Polyol Tetrabromophthalate and Its Use as a Component for Preparing Foamed Polyurethanes of Reduced Flammability

  • Macromolecular Compounds and Polymeric Materials
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Abstract

A procedure was suggested for preparing brominated polyols of reduced viscosity for the synthesis of foamed polyurethanes of reduced flammability. The flame-retarding action of the synthesized polyol tetrabromophthalate in polyurethane was studied in comparison with that of other widely used flame retardants. Evaluation of the effect exerted on the flammability of the polurethane compound by the polyol tetrabromophthalate synthesized, melamine, and aluminum hydroxide shows that all the samples containing flame retardants are self-extinguishing. The shortest combustion time was observed for the sample containing 6% polyol tetrabromophthalate synthesized. The sample containing as a flame retardant additive solely the synthesized polyole tetrabromophthalate also exhibits the highest performance as a heat-insulating material from the viewpoint of thermal conductivity.

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Acknowledgments

The authors are grateful to Cand. Sci. (Chem.) A.A. Gorbunov (Institute of Technical Chemistry, Ural Branch, Russian Academy of Sciences) for the assistance in the discussion of the results of GCMS and NMR analyses.

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Authors and Affiliations

  1. Institute of Technical Chemistry-Branch of the Perm Federal Research Center, Ural Branch, Russian Academy of Sciences, Perm, Russia

    E. A. Lebedeva, I. N. Lebedev, S. A. Astaf’eva, S. N. Lysenko & T. E. Oshchepkova

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  1. E. A. Lebedeva
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  2. I. N. Lebedev
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  3. S. A. Astaf’eva
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  4. S. N. Lysenko
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  5. T. E. Oshchepkova
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Correspondence to E. A. Lebedeva.

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Russian Text © The Author(s), 2019, published in Zhurnal Prikladnoi Khimii, 2019, Vol. 92, No. 5, pp. 639–648.

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Lebedeva, E.A., Lebedev, I.N., Astaf’eva, S.A. et al. Synthesis of Polyol Tetrabromophthalate and Its Use as a Component for Preparing Foamed Polyurethanes of Reduced Flammability. Russ J Appl Chem 92, 672–681 (2019). https://doi.org/10.1134/S1070427219050148

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  • DOI: https://doi.org/10.1134/S1070427219050148

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