Abstract
By-products formed in the conversion of vegetable biomass (multicomponent tar) were studied in comparison with the target products of the process (5-hydroxymethylfurfural, 2,5-diformylfuran) as inhibitors of corrosion of low-carbon steel in sulfuric acid at temperatures of 25-90°C. The gravimetric method was used to determine the inhibiting effect of additives. All these additives exhibit medium protective effects in an acid medium, with the degree of protection in 1 M sulfuric acid at room temperature exceeding 80%. The potentiody-namic polarization method was used to determine the influence exerted by the additives on partial reactions of the corrosion process. It was shown that the tar and 2,5-diformylfuran behave as additives of the cathodic type, and 5-hydroxymethylfurfural, as that of a mixed type. Temperature-kinetic calculations were used to determine the mechanism of action of the inhibitors. The corrosion process occurs in the presence of additives predominantly under the kinetic control.
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Belousova, N.A., Grigor'ev, V.P., Plekhanova, E.V., and Shpan'ko, S.P., Korroz.: Mater., Zashch., 2015, no. 8, pp. 13–17.
Khaidarova, G.R., Islamutdinova, A.A., Dmitriev, Yu. K., Sidorov, G.M., and Ivanov, A.N., Neftegaz. Delo, 2015, vol. 13, no. 4, pp. 163–168.
Chernyshev, V.M., Kravchenko, O.A., and Ananikov, V.P., Russ. Chem. Rev., 2017, vol. 86, no. 5, pp. 357–387.
Liu, B. and Zhang, Z., ChemSusChem, 2016, vol. 9, no. 16, pp. 2015–2036.
Kashparova, V.P., Cher nyshev, V.M., Khokhlova, E.A., Galkin, K.I., and Ana nikov, V.P., Russ. Chem. Bull., 2015, vol. 64, no. 5, pp. 1069–1073.
Klushin, V.A., Kashpa rova, V.P., Kravchenko, O.A., Smirnova, N.V., Cherny shev, V.M., Ananikov, V.P., Galkin, K.I., and Krivodae va, E.A., Russ. J. Org. Chem., 2016, vol. 52, no. 6, pp. 767–771.
Dutta, S., De, S., and Saha, B., Biomass Bioenergy, 2013, vol. 55, pp. 355–369.
Van Putten, R.-J., Van Der Waal, J.C., De Jong, E., Rasrendra, C.B., Heeres, H.J., and De Vries, J.G., Chem. Rev., 2013, vol. 113, no. 3, pp. 1499–1597.
Kashparov, I.I., Klushin, V.A., Vinokurov, I.P., Zuben-ko, A.F., Kashparova, V.P., and Smirnova, N.V., Al'tern. Energ. Ekol., 2017, nos. 19–21, pp. 116–125.
Chernysheva, D.V., Chus, Yu. A., Klushin, V. A., Las-tovina, T.A., Pudova, L.S., Smirnova, N.V., Kravchen-ko, O.A., Chernyshev, V.M., and Ananikov, V.P., Sustainable Utilization of Biomass Refinery Wastes for Accessing Activated Carbons and Supercapacitor Electrode Materials, ChemSusChem, 2018. https://onlinelibrary.wiley.com/doi/10.1002/cssc.201801757 (Cited: 15 Sept., 2018).
Machnikova, E., Whitmire, K.H., and Hackerman, N., Electrochim. Acta, 2008, vol. 53, no. 20, pp. 6024–6032.
Khaled, K.F., J. Electrochem. Soc., 2010, vol. 157, no. 3, pp. C116–C124.
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Russian Text © The Author(s), 2019, published in Zhurnal Prikladnoi Khimii, 2019, Vol. 92, No. 5, pp. 585–589.
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Mishurov, V.I., Shubina, E.N., Klushin, V.A. et al. Biomass Conversion Products as Steel Corrosion Inhibitors. Russ J Appl Chem 92, 620–624 (2019). https://doi.org/10.1134/S1070427219050069
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DOI: https://doi.org/10.1134/S1070427219050069