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Detection of Carbon Monoxide in Humid Air with Double-Layer Structures Based on Semiconducting Metal Oxides and Silicalite

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Abstract

Double-layer structures based on gas-sensitive semiconducting metal oxides and silicalite-1 were tested in detection of carbon monoxide in humid air. Pure tin dioxide and that modified with antimony and palladium served as materials of the sensitive layer. Upon deposition of a silicalite-1 layer on SnO2 and SnO2/PdOx, the signal for CO in dry air at room measurement temperature (T = 25°C) grows, but an increase in the air humidity results in that the sensor sensitivity fully disappears. Raising the measurement temperature to 100°C makes weaker the adverse effect of the humidity. The double-layer structure containing the SnO2(Sb)/PdOx nanocomposite is characterized by the most stable sensor signal that is independent of the air humidity within the range RH = 4‒65%.

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Authors and Affiliations

  1. Lomonosov Moscow State University, Moscow, 119991, Russia

    D. G. Gulevich, A. V. Marikutsa, M. N. Rumyantseva, P. B. Fabrichnyi, T. B. Shatalova & A. M. Gas’kov

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  1. D. G. Gulevich
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  2. A. V. Marikutsa
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  3. M. N. Rumyantseva
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  4. P. B. Fabrichnyi
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  5. T. B. Shatalova
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  6. A. M. Gas’kov
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Corresponding author

Correspondence to M. N. Rumyantseva.

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Original Russian Text © D.G. Gulevich, A.V. Marikutsa, M.N. Rumyantseva, P.B. Fabrichnyi, T.B. Shatalova, A.M. Gas’kov, 2018, published in Zhurnal Prikladnoi Khimii, 2018, Vol. 91, No. 10, pp. 1480−1490.

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Gulevich, D.G., Marikutsa, A.V., Rumyantseva, M.N. et al. Detection of Carbon Monoxide in Humid Air with Double-Layer Structures Based on Semiconducting Metal Oxides and Silicalite. Russ J Appl Chem 91, 1671–1679 (2018). https://doi.org/10.1134/S1070427218100154

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  • DOI: https://doi.org/10.1134/S1070427218100154

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