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1,9-Dicarbonyl-2,8-dioxo-butyne-ester Ferrocenophane: Synthesis, Structure and Recognition Properties for Co2+ and Cu2+ Ions

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Abstract

An efficient highly diluted synthetic approach to the synthesis of 1,9-dicarbonyl-2,8-dioxo-butyne ester ferrocenophane (L) has been developed. The title compound was characterized by IR, UV, FL, 1H NMR, spectroscopies, elemental analysis and so on. Further complex L shows fluorescence responses to Co2+ and Cu2+ in CH3OH, The results indicate that the complex could be applied in multianayte detection. The binding ability of receptor L CH3OH was tested for various cations (Co2+, Cu2+, Zn2+, and Ni2+ in water) and the binding constants for Co2+ and Cu2+ were the computed, having a distinct absorbance shift. The receptor is a very attractive array because its distinct absorbance shift profile in a semi-aqueous phase, making it applicable in the area of biology, environmental sciences and material chemistry.

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References

  1. Vicente, M.C., Burguete, M.I., Galindo, F., Izquierdo, M.A., Kumar, D.K., and White, A.J., J. Org. Chem., 2012, vol. 77, p. 490.

    Article  Google Scholar 

  2. Jin, C., Zhang, M., Deng, C., Guan, Y.F., Gong, J., and Zhu, D.R., Tetrahedron Lett., 2013, vol. 54, p. 796.

    Article  CAS  Google Scholar 

  3. Kondo, S.I., Bie, Y., and Yamamura, M., Org. Lett., 2013, vol. 15, p. 520.

    Article  CAS  Google Scholar 

  4. Chandra, B., Mahanta, S.P., Pati, N.N., Baskaran, S., Kanaparthi, R.K., and Sivasankar, C., Org. Lett., 2013, vol. 15, p. 306.

    Article  CAS  Google Scholar 

  5. Wei, T.B., Zhang, P., Shi, B.B., Chen, P., Lin, Q., Liu, J., and Zhang, Y.M., Dye. Pigm., 2013, vol. 97, p. 297.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Key Laboratory of Synthetic and Natural Chemistry of the Ministry of Education, Chemical Engineering Institute, the Yu-Lin University of Yulin, Chongwen Avenue 4, Yulin, Shaanxi Province, 719000, People’s Republic of China

    Xiaoju Liu, Guoyu Ren, Xiangrong Ma, Yulin Xiang & Liguo Gao

  2. Department of Applied Chemistry, School of Natural and Applied Sciences, Northwestern Polytechnical University, Xi’an, Shaanxi, 710129, China

    Xiaoyan Ma

Authors
  1. Xiaoju Liu
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  2. Guoyu Ren
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  3. Xiangrong Ma
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  4. Yulin Xiang
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  5. Liguo Gao
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  6. Xiaoyan Ma
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Correspondence to Xiaoju Liu.

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The text was submitted by the authors in English.

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Liu, X., Ren, G., Ma, X. et al. 1,9-Dicarbonyl-2,8-dioxo-butyne-ester Ferrocenophane: Synthesis, Structure and Recognition Properties for Co2+ and Cu2+ Ions. Russ J Appl Chem 90, 2016–2018 (2017). https://doi.org/10.1134/S1070427217120187

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  • DOI: https://doi.org/10.1134/S1070427217120187

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