Advertisement

Russian Journal of Applied Chemistry

, Volume 90, Issue 12, pp 2016–2018 | Cite as

1,9-Dicarbonyl-2,8-dioxo-butyne-ester Ferrocenophane: Synthesis, Structure and Recognition Properties for Co2+ and Cu2+ Ions

  • Xiaoju Liu
  • Guoyu Ren
  • Xiangrong Ma
  • Yulin Xiang
  • Liguo Gao
  • Xiaoyan Ma
Various Technological Processes
  • 17 Downloads

Abstract

An efficient highly diluted synthetic approach to the synthesis of 1,9-dicarbonyl-2,8-dioxo-butyne ester ferrocenophane (L) has been developed. The title compound was characterized by IR, UV, FL, 1H NMR, spectroscopies, elemental analysis and so on. Further complex L shows fluorescence responses to Co2+ and Cu2+ in CH3OH, The results indicate that the complex could be applied in multianayte detection. The binding ability of receptor L CH3OH was tested for various cations (Co2+, Cu2+, Zn2+, and Ni2+ in water) and the binding constants for Co2+ and Cu2+ were the computed, having a distinct absorbance shift. The receptor is a very attractive array because its distinct absorbance shift profile in a semi-aqueous phase, making it applicable in the area of biology, environmental sciences and material chemistry.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    Vicente, M.C., Burguete, M.I., Galindo, F., Izquierdo, M.A., Kumar, D.K., and White, A.J., J. Org. Chem., 2012, vol. 77, p. 490.CrossRefGoogle Scholar
  2. 2.
    Jin, C., Zhang, M., Deng, C., Guan, Y.F., Gong, J., and Zhu, D.R., Tetrahedron Lett., 2013, vol. 54, p. 796.CrossRefGoogle Scholar
  3. 3.
    Kondo, S.I., Bie, Y., and Yamamura, M., Org. Lett., 2013, vol. 15, p. 520.CrossRefGoogle Scholar
  4. 4.
    Chandra, B., Mahanta, S.P., Pati, N.N., Baskaran, S., Kanaparthi, R.K., and Sivasankar, C., Org. Lett., 2013, vol. 15, p. 306.CrossRefGoogle Scholar
  5. 5.
    Wei, T.B., Zhang, P., Shi, B.B., Chen, P., Lin, Q., Liu, J., and Zhang, Y.M., Dye. Pigm., 2013, vol. 97, p. 297.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • Xiaoju Liu
    • 1
  • Guoyu Ren
    • 1
  • Xiangrong Ma
    • 1
  • Yulin Xiang
    • 1
  • Liguo Gao
    • 1
  • Xiaoyan Ma
    • 2
  1. 1.Key Laboratory of Synthetic and Natural Chemistry of the Ministry of Education, Chemical Engineering Institutethe Yu-Lin University of YulinYulin, Shaanxi ProvincePeople’s Republic of China
  2. 2.Department of Applied Chemistry, School of Natural and Applied SciencesNorthwestern Polytechnical UniversityXi’an, ShaanxiChina

Personalised recommendations